iClick synthesis of network metallopolymers
Described is an approach to preparing the first iClick network metallopolymers with porous properties. Treating digoldazido complex 2-AuN3 with trigoldacetylide 3-AuPPh3 or 3-AuPEt3, trialkyne 3-H, tetragoldacetylide 4-AuPPh3, or tetraalkyne 4-H in CH2Cl2 affords five iClick network metallopolymers 5-AuPPh3, 5-AuPEt3, 5-H, 6-AuPPh3, and 6-H. Confirmation of the iClick network metallopolymers comes from FTIR, 13C solid-state cross-coupling magic angle spinning (CPMAS) NMR spectroscopy, thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), and nitrogen and CO2 sorption analysis. Employing model complexes 7-AuPPh3, 7-AuPEt3, 7-H, 8-AuPPh3, and 8-H provides structural insights due to the insolubility of iClick network metallopolymers.
| Medienart: |
E-Artikel |
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| Erscheinungsjahr: |
2022 |
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| Erschienen: |
2022 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:51 |
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| Enthalten in: |
Dalton transactions (Cambridge, England : 2003) - 51(2022), 48 vom: 13. Dez., Seite 18520-18527 |
| Sprache: |
Englisch |
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| Beteiligte Personen: |
Shen, Yu-Hsuan [VerfasserIn] |
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| Links: |
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| Themen: |
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| Anmerkungen: |
Date Completed 14.12.2022 Date Revised 11.05.2023 published: Electronic Citation Status MEDLINE |
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| doi: |
10.1039/d2dt01624a |
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| funding: |
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| Förderinstitution / Projekttitel: |
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| PPN (Katalog-ID): |
NLM349573913 |
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| 520 | |a Described is an approach to preparing the first iClick network metallopolymers with porous properties. Treating digoldazido complex 2-AuN3 with trigoldacetylide 3-AuPPh3 or 3-AuPEt3, trialkyne 3-H, tetragoldacetylide 4-AuPPh3, or tetraalkyne 4-H in CH2Cl2 affords five iClick network metallopolymers 5-AuPPh3, 5-AuPEt3, 5-H, 6-AuPPh3, and 6-H. Confirmation of the iClick network metallopolymers comes from FTIR, 13C solid-state cross-coupling magic angle spinning (CPMAS) NMR spectroscopy, thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), and nitrogen and CO2 sorption analysis. Employing model complexes 7-AuPPh3, 7-AuPEt3, 7-H, 8-AuPPh3, and 8-H provides structural insights due to the insolubility of iClick network metallopolymers | ||
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| 700 | 1 | |a Abboud, Khalil A |e verfasserin |4 aut | |
| 700 | 1 | |a Schanze, Kirk S |e verfasserin |4 aut | |
| 700 | 1 | |a Veige, Adam S |e verfasserin |4 aut | |
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