P/N-Heteroleptic Cu(I)-Photosensitizer-Catalyzed [3 + 2] Regiospecific Annulation of Aminocyclopropanes and Functionalized Alkynes
We report here a regiospecific [3 + 2] annulation between aminocyclopropanes and various functionalized alkynes enabled by a P/N-heteroleptic Cu(I) photosensitizer under photoredox catalysis conditions. Thus, a divergent construction of 3-aminocyclopentene derivatives including methylsulfonyl-, arylsulfonyl-, chloro-, ester-, and trifluoromethyl-functionalized aminocyclopentenes could be achieved with advantages of high regioselectivity, broad substrate compatibility, and mild and environmentally benign reaction conditions.
| Medienart: |
E-Artikel |
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| Erscheinungsjahr: |
2022 |
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| Erschienen: |
2022 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:87 |
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| Enthalten in: |
The Journal of organic chemistry - 87(2022), 22 vom: 18. Nov., Seite 15571-15581 |
| Sprache: |
Englisch |
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| Beteiligte Personen: |
Chen, Lailin [VerfasserIn] |
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| Links: |
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| Themen: |
Alkynes |
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| Anmerkungen: |
Date Completed 21.11.2022 Date Revised 06.01.2023 published: Print-Electronic Citation Status MEDLINE |
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| doi: |
10.1021/acs.joc.2c02138 |
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| funding: |
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| Förderinstitution / Projekttitel: |
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| PPN (Katalog-ID): |
NLM348360282 |
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| 245 | 1 | 0 | |a P/N-Heteroleptic Cu(I)-Photosensitizer-Catalyzed [3 + 2] Regiospecific Annulation of Aminocyclopropanes and Functionalized Alkynes |
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| 500 | |a Date Revised 06.01.2023 | ||
| 500 | |a published: Print-Electronic | ||
| 500 | |a Citation Status MEDLINE | ||
| 520 | |a We report here a regiospecific [3 + 2] annulation between aminocyclopropanes and various functionalized alkynes enabled by a P/N-heteroleptic Cu(I) photosensitizer under photoredox catalysis conditions. Thus, a divergent construction of 3-aminocyclopentene derivatives including methylsulfonyl-, arylsulfonyl-, chloro-, ester-, and trifluoromethyl-functionalized aminocyclopentenes could be achieved with advantages of high regioselectivity, broad substrate compatibility, and mild and environmentally benign reaction conditions | ||
| 650 | 4 | |a Journal Article | |
| 650 | 4 | |a Research Support, Non-U.S. Gov't | |
| 650 | 7 | |a Alkynes |2 NLM | |
| 650 | 7 | |a Photosensitizing Agents |2 NLM | |
| 700 | 1 | |a Li, Ya |e verfasserin |4 aut | |
| 700 | 1 | |a Han, Mingfeng |e verfasserin |4 aut | |
| 700 | 1 | |a Peng, Yun |e verfasserin |4 aut | |
| 700 | 1 | |a Chen, Xiahe |e verfasserin |4 aut | |
| 700 | 1 | |a Xiang, Siwei |e verfasserin |4 aut | |
| 700 | 1 | |a Gao, Hong |e verfasserin |4 aut | |
| 700 | 1 | |a Lu, Tianhao |e verfasserin |4 aut | |
| 700 | 1 | |a Luo, Shu-Ping |e verfasserin |4 aut | |
| 700 | 1 | |a Zhou, Bingwei |e verfasserin |4 aut | |
| 700 | 1 | |a Wu, Huayue |e verfasserin |4 aut | |
| 700 | 1 | |a Yang, Yun-Fang |e verfasserin |4 aut | |
| 700 | 1 | |a Liu, Yunkui |e verfasserin |4 aut | |
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