Two ambuic acid dimers derived from homo-endo Diels-Alder reaction from Pestalotiopsis versicolor

Two new dimers of ambuic acid, pestaloversicoloric acids A (1) and B (2), and a known derivative, 13(S)-hydroxyambuic acid (3), were isolated from the static fermentation product of Pestalotiopsis versicolor. The structural identification was accomplished via analyses on the data of HR-MS, 1 D and 2 D NMR, and ECD. Different from the well-known exo-type dimer, torreyanic acid, compounds 1 and 2 represent the first example of endo-type product derived from the intermolecular Diels-Alder reaction of two molecules of ambuic acid derivative with the identical absolute stereochemistry.

Medienart:

E-Artikel

Erscheinungsjahr:

2023

Erschienen:

2023

Enthalten in:

Zur Gesamtaufnahme - volume:25

Enthalten in:

Journal of Asian natural products research - 25(2023), 7 vom: 20. Juli, Seite 641-649

Sprache:

Englisch

Beteiligte Personen:

Li, Dan-Yi [VerfasserIn]
Zhang, Xiao-Ling [VerfasserIn]
Li, Zhan-Lin [VerfasserIn]

Links:

Volltext

Themen:

Ambuic acid
Cyclohexanones
Diels-Alder reaction
Endo-product
Journal Article
Pestalotiopsis versicolor

Anmerkungen:

Date Completed 19.07.2023

Date Revised 19.07.2023

published: Print-Electronic

Citation Status MEDLINE

doi:

10.1080/10286020.2022.2132480

funding:

Förderinstitution / Projekttitel:

PPN (Katalog-ID):

NLM347792804