Selective C-S Bond Constructions Using Inorganic Sulfurs via Photoinduced Electron Donor-Acceptor Activation
By complementing traditional transition metal catalysis, photoinduced catalysis has emerged as a versatile and sustainable way to achieve carbon-heteroatom bond formation. This work discloses a visible-light-induced reaction for the formation of a C-S bond from aryl halides and inorganic sulfuration agents via electron donor-acceptor (EDA) complex photocatalysis. Divergent formations of organic sulfide and disulfide have been demonstrated under mild conditions. Preliminary mechanistic studies suggest that visible-light-induced intracomplex charge transfer within the monosulfide-anion-containing EDA complex permits the C-S bond construction reactivity.
| Medienart: |
E-Artikel |
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| Erscheinungsjahr: |
2022 |
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| Erschienen: |
2022 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:87 |
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| Enthalten in: |
The Journal of organic chemistry - 87(2022), 21 vom: 04. Nov., Seite 14241-14249 |
| Sprache: |
Englisch |
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| Beteiligte Personen: |
Yang, Fan [VerfasserIn] |
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| Anmerkungen: |
Date Revised 07.11.2022 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
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| doi: |
10.1021/acs.joc.2c01750 |
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| funding: |
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NLM347350054 |
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| 520 | |a By complementing traditional transition metal catalysis, photoinduced catalysis has emerged as a versatile and sustainable way to achieve carbon-heteroatom bond formation. This work discloses a visible-light-induced reaction for the formation of a C-S bond from aryl halides and inorganic sulfuration agents via electron donor-acceptor (EDA) complex photocatalysis. Divergent formations of organic sulfide and disulfide have been demonstrated under mild conditions. Preliminary mechanistic studies suggest that visible-light-induced intracomplex charge transfer within the monosulfide-anion-containing EDA complex permits the C-S bond construction reactivity | ||
| 650 | 4 | |a Journal Article | |
| 700 | 1 | |a He, Gu-Cheng |e verfasserin |4 aut | |
| 700 | 1 | |a Sun, Shao-Han |e verfasserin |4 aut | |
| 700 | 1 | |a Song, Ting-Ting |e verfasserin |4 aut | |
| 700 | 1 | |a Min, Xiang-Ting |e verfasserin |4 aut | |
| 700 | 1 | |a Ji, Ding-Wei |e verfasserin |4 aut | |
| 700 | 1 | |a Guo, Shi-Yu |e verfasserin |4 aut | |
| 700 | 1 | |a Chen, Qing-An |e verfasserin |4 aut | |
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