Mn doping improves in-situ H2O2 generation and activation in electro-Fenton process by Fe/MnCC cathode using high-temperature shock technique
Copyright © 2022 Elsevier Ltd. All rights reserved..
Fe/Mncarbon cloth (CC) was successfully fabricated through high-temperature shock (HTS) technique and used as cathode modification in heterogeneous electro-Fenton (hetero-EF) process for methylisothiazolinone (MIT) degradation. The nanocrystalline on Fe/Mn@CC electrode is doped with Fe and Mn oxides and coated with carbon layer, which could markedly enhance the electrocatalysis with high electro-chemical active area and low resistance. Fe/Mn@CC modified cathode can efficiently in-situ produce and activate H2O2, showing high electrocatalytic activity to MIT degradation. The 95.2% MIT degradation with in 100 min were achieved under the condition of 30 mA current, 0.75 L min-1 aeration intensity and initial pH = 3. Based on the CV curves and stability test, the high degradation activity revealed the kinetically beneficial regeneration of FeII/MnII in Fe/Mn@CC and activation of H2O2. The electron transfer between FeII/III and MnII/III, together with the direct FeII/MnII regeneration on the cathode, could markedly promote the H2O2 utilization, and eventually lead to MIT degradation.
| Medienart: |
E-Artikel |
|---|
| Erscheinungsjahr: |
2022 |
|---|---|
| Erschienen: |
2022 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:307 |
|---|---|
| Enthalten in: |
Chemosphere - 307(2022), Pt 3 vom: 15. Nov., Seite 136074 |
| Sprache: |
Englisch |
|---|
| Beteiligte Personen: |
Li, Yanchao [VerfasserIn] |
|---|
| Links: |
|---|
| Anmerkungen: |
Date Completed 29.09.2022 Date Revised 29.09.2022 published: Print-Electronic Citation Status MEDLINE |
|---|
| doi: |
10.1016/j.chemosphere.2022.136074 |
|---|
| funding: |
|
|---|---|
| Förderinstitution / Projekttitel: |
|
| PPN (Katalog-ID): |
NLM345058089 |
|---|
| LEADER | 01000naa a22002652 4500 | ||
|---|---|---|---|
| 001 | NLM345058089 | ||
| 003 | DE-627 | ||
| 005 | 20231226024215.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 231226s2022 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1016/j.chemosphere.2022.136074 |2 doi | |
| 028 | 5 | 2 | |a pubmed24n1150.xml |
| 035 | |a (DE-627)NLM345058089 | ||
| 035 | |a (NLM)35987271 | ||
| 035 | |a (PII)S0045-6535(22)02567-X | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rakwb | ||
| 041 | |a eng | ||
| 100 | 1 | |a Li, Yanchao |e verfasserin |4 aut | |
| 245 | 1 | 3 | |a Mn doping improves in-situ H2O2 generation and activation in electro-Fenton process by Fe/MnCC cathode using high-temperature shock technique |
| 264 | 1 | |c 2022 | |
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a ƒaComputermedien |b c |2 rdamedia | ||
| 338 | |a ƒa Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a Date Completed 29.09.2022 | ||
| 500 | |a Date Revised 29.09.2022 | ||
| 500 | |a published: Print-Electronic | ||
| 500 | |a Citation Status MEDLINE | ||
| 520 | |a Copyright © 2022 Elsevier Ltd. All rights reserved. | ||
| 520 | |a Fe/Mncarbon cloth (CC) was successfully fabricated through high-temperature shock (HTS) technique and used as cathode modification in heterogeneous electro-Fenton (hetero-EF) process for methylisothiazolinone (MIT) degradation. The nanocrystalline on Fe/Mn@CC electrode is doped with Fe and Mn oxides and coated with carbon layer, which could markedly enhance the electrocatalysis with high electro-chemical active area and low resistance. Fe/Mn@CC modified cathode can efficiently in-situ produce and activate H2O2, showing high electrocatalytic activity to MIT degradation. The 95.2% MIT degradation with in 100 min were achieved under the condition of 30 mA current, 0.75 L min-1 aeration intensity and initial pH = 3. Based on the CV curves and stability test, the high degradation activity revealed the kinetically beneficial regeneration of FeII/MnII in Fe/Mn@CC and activation of H2O2. The electron transfer between FeII/III and MnII/III, together with the direct FeII/MnII regeneration on the cathode, could markedly promote the H2O2 utilization, and eventually lead to MIT degradation | ||
| 650 | 4 | |a Journal Article | |
| 650 | 4 | |a H(2)O(2) activation | |
| 650 | 4 | |a Heterogeneous elecrto-Fenton | |
| 650 | 4 | |a High-temperature shock | |
| 650 | 4 | |a Methylisothiazolinone | |
| 650 | 4 | |a Synergistic activation | |
| 650 | 7 | |a Ferrous Compounds |2 NLM | |
| 650 | 7 | |a Oxides |2 NLM | |
| 650 | 7 | |a Water Pollutants, Chemical |2 NLM | |
| 650 | 7 | |a Carbon |2 NLM | |
| 650 | 7 | |a 7440-44-0 |2 NLM | |
| 650 | 7 | |a Hydrogen Peroxide |2 NLM | |
| 650 | 7 | |a BBX060AN9V |2 NLM | |
| 700 | 1 | |a Wang, Can |e verfasserin |4 aut | |
| 700 | 1 | |a Pan, Shuang |e verfasserin |4 aut | |
| 700 | 1 | |a Zhao, Xin |e verfasserin |4 aut | |
| 700 | 1 | |a Liu, Ning |e verfasserin |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Chemosphere |d 1994 |g 307(2022), Pt 3 vom: 15. Nov., Seite 136074 |w (DE-627)NLM074698028 |x 1879-1298 |7 nnns |
| 773 | 1 | 8 | |g volume:307 |g year:2022 |g number:Pt 3 |g day:15 |g month:11 |g pages:136074 |
| 856 | 4 | 0 | |u http://dx.doi.org/10.1016/j.chemosphere.2022.136074 |3 Volltext |
| 912 | |a GBV_USEFLAG_A | ||
| 912 | |a GBV_NLM | ||
| 951 | |a AR | ||
| 952 | |d 307 |j 2022 |e Pt 3 |b 15 |c 11 |h 136074 | ||