Synthesis of 10-Aza-9-oxakalkitoxin by N-O Bond Formation
We describe a formal synthesis of 10-aza-9-oxakalkitoxin, the hydroxalog of the cytotoxic marine natural product kalkitoxin, that features Mukaiyama Markovnikov silyl peroxidation of a terminal alkene and N-O bond formation as the central enabling steps.
| Medienart: |
E-Artikel |
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| Erscheinungsjahr: |
2022 |
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| Erschienen: |
2022 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:24 |
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| Enthalten in: |
Organic letters - 24(2022), 9 vom: 11. März, Seite 1833-1836 |
| Sprache: |
Englisch |
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| Beteiligte Personen: |
Upadhyaya, Kapil [VerfasserIn] |
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| Anmerkungen: |
Date Completed 14.04.2022 Date Revised 12.03.2023 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
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| doi: |
10.1021/acs.orglett.2c00349 |
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| funding: |
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NLM337570779 |
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| 520 | |a We describe a formal synthesis of 10-aza-9-oxakalkitoxin, the hydroxalog of the cytotoxic marine natural product kalkitoxin, that features Mukaiyama Markovnikov silyl peroxidation of a terminal alkene and N-O bond formation as the central enabling steps | ||
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