Synthesis of Poly(ionic Liquid)s-block-poly(methyl Methacrylate) Copolymer-Grafted Silica Particle Brushes with Enhanced CO2 Permeability and Mechanical Performance
Poly(ionic liquid) (PIL)-based block copolymers are of particular interest as they combine the specific properties of PILs with the self-assembling behaviors of block copolymers, broadening the range of potential applications for PIL-based materials. In this work, three particle brushes: SiO2-g-poly(methyl methacrylate) (PMMA), SiO2-g-PIL, and SiO2-g-PMMA-b-PIL were prepared through surface-initiated atom transfer radical polymerization. Unlike the homogeneous homopolymer particle brushes, the block copolymer particle brush SiO2-g-PMMA-b-PIL exhibited a bimodal chain architecture and unique phase-separated morphology, which were confirmed by size-exclusion chromatography and transmission electron microscopy. In addition, the influence of the introduction of the PMMA segment on the gas separation and mechanical performance of the PIL-containing block copolymer particle brushes were investigated. A significant improvement of Young's modulus was observed in the SiO2-g-PMMA-b-PIL compared to the SiO2-g-PIL bulk films; meanwhile, their gas separation performances (CO2 permeability and CO2/N2 selectivity) were the same, which demonstrates the possibility of improving the mechanical properties of PIL-based particle brushes without compromising their gas separation performance.
Medienart: |
E-Artikel |
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Erscheinungsjahr: |
2021 |
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Erschienen: |
2021 |
Enthalten in: |
Zur Gesamtaufnahme - volume:37 |
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Enthalten in: |
Langmuir : the ACS journal of surfaces and colloids - 37(2021), 36 vom: 14. Sept., Seite 10875-10881 |
Sprache: |
Englisch |
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Beteiligte Personen: |
Wang, Zongyu [VerfasserIn] |
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Anmerkungen: |
Date Revised 14.09.2021 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
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doi: |
10.1021/acs.langmuir.1c01877 |
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funding: |
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Förderinstitution / Projekttitel: |
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PPN (Katalog-ID): |
NLM330024094 |
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520 | |a Poly(ionic liquid) (PIL)-based block copolymers are of particular interest as they combine the specific properties of PILs with the self-assembling behaviors of block copolymers, broadening the range of potential applications for PIL-based materials. In this work, three particle brushes: SiO2-g-poly(methyl methacrylate) (PMMA), SiO2-g-PIL, and SiO2-g-PMMA-b-PIL were prepared through surface-initiated atom transfer radical polymerization. Unlike the homogeneous homopolymer particle brushes, the block copolymer particle brush SiO2-g-PMMA-b-PIL exhibited a bimodal chain architecture and unique phase-separated morphology, which were confirmed by size-exclusion chromatography and transmission electron microscopy. In addition, the influence of the introduction of the PMMA segment on the gas separation and mechanical performance of the PIL-containing block copolymer particle brushes were investigated. A significant improvement of Young's modulus was observed in the SiO2-g-PMMA-b-PIL compared to the SiO2-g-PIL bulk films; meanwhile, their gas separation performances (CO2 permeability and CO2/N2 selectivity) were the same, which demonstrates the possibility of improving the mechanical properties of PIL-based particle brushes without compromising their gas separation performance | ||
650 | 4 | |a Journal Article | |
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700 | 1 | |a Chen, Jihua |e verfasserin |4 aut | |
700 | 1 | |a Arnould, Mark |e verfasserin |4 aut | |
700 | 1 | |a Popovs, Ilja |e verfasserin |4 aut | |
700 | 1 | |a Mahurin, Shannon M |e verfasserin |4 aut | |
700 | 1 | |a Chen, Hao |e verfasserin |4 aut | |
700 | 1 | |a Wang, Tao |e verfasserin |4 aut | |
700 | 1 | |a Dai, Sheng |e verfasserin |4 aut | |
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