Effect of Cu Ion Concentration on Microstructures and Mechanical Properties of Nanotwinned Cu Foils Fabricated by Rotary Electroplating
Rotary electroplating was employed to fabricate high-strength nanotwinned copper (nt-Cu) foils serving as a current collector for high energy-density lithium ion batteries (LIBs). The effect of Cu ion concentration on the microstructural and mechanical properties of the nt-Cu foils was then investigated. Formation of nano-scaled grains was found at the bottom. Its size gradually increases toward the top surface to form a microstructural mixture of gradient nano-scaled and columnar grains in the upper region. Experimental results show that the grains and elongation of the nt-Cu foils increase with increasing concentration of Cu ions. However, a trade-off between tensile strength and elongation is present. The elongation of nt-Cu foils has been enhanced by 22% (from 3.1% to 3.8%) while 8.3% and 3.9% reductions in ultimate tensile strength (UTS) and yield stress (YS) are seen. The current study shows a promising method to tune and optimize the microstructure and mechanical properties of such nt-Cu foils for various applications.
| Medienart: |
E-Artikel |
|---|
| Erscheinungsjahr: |
2021 |
|---|---|
| Erschienen: |
2021 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:11 |
|---|---|
| Enthalten in: |
Nanomaterials (Basel, Switzerland) - 11(2021), 8 vom: 22. Aug. |
| Sprache: |
Englisch |
|---|
| Beteiligte Personen: |
Hung, Yu-Wen [VerfasserIn] |
|---|
| Links: |
|---|
| Themen: |
Columnar grain structures |
|---|
| Anmerkungen: |
Date Revised 31.08.2021 published: Electronic Citation Status PubMed-not-MEDLINE |
|---|
| doi: |
10.3390/nano11082135 |
|---|
| funding: |
|
|---|---|
| Förderinstitution / Projekttitel: |
|
| PPN (Katalog-ID): |
NLM329868721 |
|---|
| LEADER | 01000naa a22002652 4500 | ||
|---|---|---|---|
| 001 | NLM329868721 | ||
| 003 | DE-627 | ||
| 005 | 20231225210045.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 231225s2021 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.3390/nano11082135 |2 doi | |
| 028 | 5 | 2 | |a pubmed24n1099.xml |
| 035 | |a (DE-627)NLM329868721 | ||
| 035 | |a (NLM)34443965 | ||
| 035 | |a (PII)2135 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rakwb | ||
| 041 | |a eng | ||
| 100 | 1 | |a Hung, Yu-Wen |e verfasserin |4 aut | |
| 245 | 1 | 0 | |a Effect of Cu Ion Concentration on Microstructures and Mechanical Properties of Nanotwinned Cu Foils Fabricated by Rotary Electroplating |
| 264 | 1 | |c 2021 | |
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a ƒaComputermedien |b c |2 rdamedia | ||
| 338 | |a ƒa Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a Date Revised 31.08.2021 | ||
| 500 | |a published: Electronic | ||
| 500 | |a Citation Status PubMed-not-MEDLINE | ||
| 520 | |a Rotary electroplating was employed to fabricate high-strength nanotwinned copper (nt-Cu) foils serving as a current collector for high energy-density lithium ion batteries (LIBs). The effect of Cu ion concentration on the microstructural and mechanical properties of the nt-Cu foils was then investigated. Formation of nano-scaled grains was found at the bottom. Its size gradually increases toward the top surface to form a microstructural mixture of gradient nano-scaled and columnar grains in the upper region. Experimental results show that the grains and elongation of the nt-Cu foils increase with increasing concentration of Cu ions. However, a trade-off between tensile strength and elongation is present. The elongation of nt-Cu foils has been enhanced by 22% (from 3.1% to 3.8%) while 8.3% and 3.9% reductions in ultimate tensile strength (UTS) and yield stress (YS) are seen. The current study shows a promising method to tune and optimize the microstructure and mechanical properties of such nt-Cu foils for various applications | ||
| 650 | 4 | |a Journal Article | |
| 650 | 4 | |a columnar grain structures | |
| 650 | 4 | |a concentration of Cu ions | |
| 650 | 4 | |a mechanical properties | |
| 650 | 4 | |a nanotwinned Cu | |
| 650 | 4 | |a rotary electrodeposition | |
| 700 | 1 | |a Tran, Dinh-Phuc |e verfasserin |4 aut | |
| 700 | 1 | |a Chen, Chih |e verfasserin |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Nanomaterials (Basel, Switzerland) |d 2010 |g 11(2021), 8 vom: 22. Aug. |w (DE-627)NLM235444340 |x 2079-4991 |7 nnns |
| 773 | 1 | 8 | |g volume:11 |g year:2021 |g number:8 |g day:22 |g month:08 |
| 856 | 4 | 0 | |u http://dx.doi.org/10.3390/nano11082135 |3 Volltext |
| 912 | |a GBV_USEFLAG_A | ||
| 912 | |a GBV_NLM | ||
| 951 | |a AR | ||
| 952 | |d 11 |j 2021 |e 8 |b 22 |c 08 | ||