Stereospecific synthesis of chiral P-containing polyaromatics based on 7-membered P-rings
We present the stereospecific synthesis of helicenoid-based phosphepines (7-membered P-rings) as well as chiral P-containing polycyclic aromatic hydrocarbons. In these systems, an axial to central chirality transfer takes place from the BINAP moiety to the P-atom. The impact of the molecular design on the structure, the (chir)optical (including circularly polarized luminescence) and redox properties are investigated.
| Medienart: |
E-Artikel |
|---|
| Erscheinungsjahr: |
2021 |
|---|---|
| Erschienen: |
2021 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:57 |
|---|---|
| Enthalten in: |
Chemical communications (Cambridge, England) - 57(2021), 59 vom: 28. Juli, Seite 7256-7259 |
| Sprache: |
Englisch |
|---|
| Beteiligte Personen: |
Mokrai, Réka [VerfasserIn] |
|---|
| Links: |
|---|
| Themen: |
|---|
| Anmerkungen: |
Date Completed 22.07.2021 Date Revised 22.07.2021 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
|---|
| doi: |
10.1039/d1cc02293h |
|---|
| funding: |
|
|---|---|
| Förderinstitution / Projekttitel: |
|
| PPN (Katalog-ID): |
NLM327424877 |
|---|
| LEADER | 01000naa a22002652 4500 | ||
|---|---|---|---|
| 001 | NLM327424877 | ||
| 003 | DE-627 | ||
| 005 | 20231225200745.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 231225s2021 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1039/d1cc02293h |2 doi | |
| 028 | 5 | 2 | |a pubmed24n1091.xml |
| 035 | |a (DE-627)NLM327424877 | ||
| 035 | |a (NLM)34195719 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rakwb | ||
| 041 | |a eng | ||
| 100 | 1 | |a Mokrai, Réka |e verfasserin |4 aut | |
| 245 | 1 | 0 | |a Stereospecific synthesis of chiral P-containing polyaromatics based on 7-membered P-rings |
| 264 | 1 | |c 2021 | |
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a ƒaComputermedien |b c |2 rdamedia | ||
| 338 | |a ƒa Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a Date Completed 22.07.2021 | ||
| 500 | |a Date Revised 22.07.2021 | ||
| 500 | |a published: Print-Electronic | ||
| 500 | |a Citation Status PubMed-not-MEDLINE | ||
| 520 | |a We present the stereospecific synthesis of helicenoid-based phosphepines (7-membered P-rings) as well as chiral P-containing polycyclic aromatic hydrocarbons. In these systems, an axial to central chirality transfer takes place from the BINAP moiety to the P-atom. The impact of the molecular design on the structure, the (chir)optical (including circularly polarized luminescence) and redox properties are investigated | ||
| 650 | 4 | |a Journal Article | |
| 700 | 1 | |a Mocanu, Anabella |e verfasserin |4 aut | |
| 700 | 1 | |a Duffy, Matthew P |e verfasserin |4 aut | |
| 700 | 1 | |a Vives, Thomas |e verfasserin |4 aut | |
| 700 | 1 | |a Caytan, Elsa |e verfasserin |4 aut | |
| 700 | 1 | |a Dorcet, Vincent |e verfasserin |4 aut | |
| 700 | 1 | |a Roisnel, Thierry |e verfasserin |4 aut | |
| 700 | 1 | |a Nyulászi, László |e verfasserin |4 aut | |
| 700 | 1 | |a Benkő, Zoltán |e verfasserin |4 aut | |
| 700 | 1 | |a Bouit, Pierre-Antoine |e verfasserin |4 aut | |
| 700 | 1 | |a Hissler, Muriel |e verfasserin |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Chemical communications (Cambridge, England) |d 1998 |g 57(2021), 59 vom: 28. Juli, Seite 7256-7259 |w (DE-627)NLM095512322 |x 1364-548X |7 nnns |
| 773 | 1 | 8 | |g volume:57 |g year:2021 |g number:59 |g day:28 |g month:07 |g pages:7256-7259 |
| 856 | 4 | 0 | |u http://dx.doi.org/10.1039/d1cc02293h |3 Volltext |
| 912 | |a GBV_USEFLAG_A | ||
| 912 | |a GBV_NLM | ||
| 951 | |a AR | ||
| 952 | |d 57 |j 2021 |e 59 |b 28 |c 07 |h 7256-7259 | ||