Recent development in transition metal-catalysed C-H olefination
This journal is © The Royal Society of Chemistry..
Transition metal-catalysed functionalizations of inert C-H bonds to construct C-C bonds represent an ideal route in the synthesis of valuable organic molecules. Fine tuning of directing groups, catalysts and ligands has played a crucial role in selective C-H bond (sp2 or sp3) activation. Recent developments in these areas have assured a high level of regioselectivity in C-H olefination reactions. In this review, we have summarized the recent progress in the oxidative olefination of sp2 and sp3 C-H bonds with special emphasis on distal, atroposelective, non-directed sp2 and directed sp3 C-H olefination. The scope, limitation, and mechanism of various transition metal-catalysed olefination reactions have been described briefly.
| Medienart: |
E-Artikel |
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| Erscheinungsjahr: |
2021 |
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| Erschienen: |
2021 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:12 |
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| Enthalten in: |
Chemical science - 12(2021), 8 vom: 29. Jan., Seite 2735-2759 |
| Sprache: |
Englisch |
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| Beteiligte Personen: |
Ali, Wajid [VerfasserIn] |
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| Links: |
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| Anmerkungen: |
Date Revised 02.03.2024 published: Electronic Citation Status PubMed-not-MEDLINE |
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| doi: |
10.1039/d0sc05555g |
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| funding: |
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| Förderinstitution / Projekttitel: |
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| 520 | |a Transition metal-catalysed functionalizations of inert C-H bonds to construct C-C bonds represent an ideal route in the synthesis of valuable organic molecules. Fine tuning of directing groups, catalysts and ligands has played a crucial role in selective C-H bond (sp2 or sp3) activation. Recent developments in these areas have assured a high level of regioselectivity in C-H olefination reactions. In this review, we have summarized the recent progress in the oxidative olefination of sp2 and sp3 C-H bonds with special emphasis on distal, atroposelective, non-directed sp2 and directed sp3 C-H olefination. The scope, limitation, and mechanism of various transition metal-catalysed olefination reactions have been described briefly | ||
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