Soil colloids affect the aggregation and stability of biochar colloids
Copyright © 2021 Elsevier B.V. All rights reserved..
The stability of biochar colloids plays an important role in the transport and fate of contaminants and nutrients in soil. This study aimed to investigate the effects of main soil components, kaolin (Kao), goethite (Goe), and humic acid (HA) colloids on the aggregation kinetics of biochar colloids derived from dairy manure (DM), sewage sludge (SS), and wheat straw (WS). The WS biochar colloid had the highest critical coagulation concentration (CCC) (624 mM) than that of SS (200 mM) and DM (75 mM) due to its richest hydroxyl and carboxyl groups, showing the highest stability. Kao markedly improved the stability of DM and SS biochar colloids with 171% and 52.5% increase of CCC, respectively, by increasing the electrostatic repulsion of the system. However, the WS biochar colloid became more aggregated in the presence of Kao since the hydroxyl and carboxyl functional groups in WS biochar colloid could complex with Kao, generating electrostatic shielding. Goe could rapidly combine with biochar colloids via electrostatic attraction, resulting in the aggregation of SS and WS, while the aggregation rate of DM/Goe mixed colloids was inhibited. The HA increased the electrostatic repulsion of all biochar colloids through adsorbed on the surface of biochar colloids, resulting in the increased steric hindrance and stability of biochar colloids, with the CCC increased from 75 to 624 mM to 827-1012 mM. Our findings reveal that soil kaolin, goethite, and humic acid colloids have remarkable effects on the stability and aggregation of biochar colloid, which will advance understanding of the potential environmental fate and behaviors of biochar colloids.
| Medienart: |
E-Artikel |
|---|
| Erscheinungsjahr: |
2021 |
|---|---|
| Erschienen: |
2021 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:771 |
|---|---|
| Enthalten in: |
The Science of the total environment - 771(2021) vom: 01. Juni, Seite 145414 |
| Sprache: |
Englisch |
|---|
| Beteiligte Personen: |
Gui, Xiangyang [VerfasserIn] |
|---|
| Links: |
|---|
| Themen: |
16291-96-6 |
|---|
| Anmerkungen: |
Date Completed 22.03.2021 Date Revised 22.03.2021 published: Print-Electronic Citation Status MEDLINE |
|---|
| doi: |
10.1016/j.scitotenv.2021.145414 |
|---|
| funding: |
|
|---|---|
| Förderinstitution / Projekttitel: |
|
| PPN (Katalog-ID): |
NLM322926904 |
|---|
| LEADER | 01000naa a22002652 4500 | ||
|---|---|---|---|
| 001 | NLM322926904 | ||
| 003 | DE-627 | ||
| 005 | 20231225183057.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 231225s2021 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1016/j.scitotenv.2021.145414 |2 doi | |
| 028 | 5 | 2 | |a pubmed24n1076.xml |
| 035 | |a (DE-627)NLM322926904 | ||
| 035 | |a (NLM)33736183 | ||
| 035 | |a (PII)S0048-9697(21)00482-4 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rakwb | ||
| 041 | |a eng | ||
| 100 | 1 | |a Gui, Xiangyang |e verfasserin |4 aut | |
| 245 | 1 | 0 | |a Soil colloids affect the aggregation and stability of biochar colloids |
| 264 | 1 | |c 2021 | |
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a ƒaComputermedien |b c |2 rdamedia | ||
| 338 | |a ƒa Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a Date Completed 22.03.2021 | ||
| 500 | |a Date Revised 22.03.2021 | ||
| 500 | |a published: Print-Electronic | ||
| 500 | |a Citation Status MEDLINE | ||
| 520 | |a Copyright © 2021 Elsevier B.V. All rights reserved. | ||
| 520 | |a The stability of biochar colloids plays an important role in the transport and fate of contaminants and nutrients in soil. This study aimed to investigate the effects of main soil components, kaolin (Kao), goethite (Goe), and humic acid (HA) colloids on the aggregation kinetics of biochar colloids derived from dairy manure (DM), sewage sludge (SS), and wheat straw (WS). The WS biochar colloid had the highest critical coagulation concentration (CCC) (624 mM) than that of SS (200 mM) and DM (75 mM) due to its richest hydroxyl and carboxyl groups, showing the highest stability. Kao markedly improved the stability of DM and SS biochar colloids with 171% and 52.5% increase of CCC, respectively, by increasing the electrostatic repulsion of the system. However, the WS biochar colloid became more aggregated in the presence of Kao since the hydroxyl and carboxyl functional groups in WS biochar colloid could complex with Kao, generating electrostatic shielding. Goe could rapidly combine with biochar colloids via electrostatic attraction, resulting in the aggregation of SS and WS, while the aggregation rate of DM/Goe mixed colloids was inhibited. The HA increased the electrostatic repulsion of all biochar colloids through adsorbed on the surface of biochar colloids, resulting in the increased steric hindrance and stability of biochar colloids, with the CCC increased from 75 to 624 mM to 827-1012 mM. Our findings reveal that soil kaolin, goethite, and humic acid colloids have remarkable effects on the stability and aggregation of biochar colloid, which will advance understanding of the potential environmental fate and behaviors of biochar colloids | ||
| 650 | 4 | |a Journal Article | |
| 650 | 4 | |a Aggregation and stability | |
| 650 | 4 | |a Biochar colloids | |
| 650 | 4 | |a Goethite | |
| 650 | 4 | |a Humic acid | |
| 650 | 4 | |a Kaolin | |
| 650 | 7 | |a Colloids |2 NLM | |
| 650 | 7 | |a Humic Substances |2 NLM | |
| 650 | 7 | |a Soil |2 NLM | |
| 650 | 7 | |a biochar |2 NLM | |
| 650 | 7 | |a Charcoal |2 NLM | |
| 650 | 7 | |a 16291-96-6 |2 NLM | |
| 700 | 1 | |a Song, Bingqing |e verfasserin |4 aut | |
| 700 | 1 | |a Chen, Ming |e verfasserin |4 aut | |
| 700 | 1 | |a Xu, Xiaoyun |e verfasserin |4 aut | |
| 700 | 1 | |a Ren, Zhefan |e verfasserin |4 aut | |
| 700 | 1 | |a Li, Xing |e verfasserin |4 aut | |
| 700 | 1 | |a Cao, Xinde |e verfasserin |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t The Science of the total environment |d 1972 |g 771(2021) vom: 01. Juni, Seite 145414 |w (DE-627)NLM000215562 |x 1879-1026 |7 nnns |
| 773 | 1 | 8 | |g volume:771 |g year:2021 |g day:01 |g month:06 |g pages:145414 |
| 856 | 4 | 0 | |u http://dx.doi.org/10.1016/j.scitotenv.2021.145414 |3 Volltext |
| 912 | |a GBV_USEFLAG_A | ||
| 912 | |a GBV_NLM | ||
| 951 | |a AR | ||
| 952 | |d 771 |j 2021 |b 01 |c 06 |h 145414 | ||