Potential of Scenedesmus-fabricated ZnO nanorods in photocatalytic reduction of methylene blue under direct sunlight : kinetics and mechanism
Organic synthetic dyes are widely used in several industries; however, their inherent resistance to biodegradation necessitates to investigate alternative methods for the remediation of this class of hazardous substances. In the present study, a green synthesis of ZnO nanorods was achieved in a fast, environment-friendly, and safe microwave process employing algal extract. Different metabolites like sugars, proteins, fatty acids, amino acids, and vitamins present in the algal extract reduced the Zn2+ into ZnO. The XRD analysis showed that the nanostructure was a crystalline hexagonal nanorod having a crystalline size of 27.37 nm. The XPS spectra of ZnO nanorod showed characteristic peaks at binding energy 1043, 1020, 496, 137, 87, and 8 eV corresponding to Zn2p1/2, Zn2p3/2, ZnLMM, Zn3s, Zn3p, Zn3d, respectively. The synthesized ZnO nanorods were in-situ functionalized and showed strong catalytic activity in photoreduction of a model organic dye methylene blue (MB) under direct sunlight irradiation. Synthesized ZnO nanorods showed a complete (100%) reduction of model dye MB from its 10 mg/L aqueous solution. The photocatalytic degradation of MB followed the Michaelis-Menten kinetics. The rate of ZnO-catalyzed photocatalytic degradation depends on the concentrations of ZnO, pH, and sunlight irradiation. The ZnO nanorod-catalyzed photoreduction of MB involves hydroxyl radicals. Algal-mediated and microwave-assisted synthesis provides a scalable source of metal oxide nanoparticles for the remediation of dye-containing wastewaters under natural sunlight. Apart from application in the removal of dyes, ZnO nanorods are excellent material for applications in semiconductors, electronics, optics, bio-imaging, and drug delivery.
Medienart: |
E-Artikel |
---|
Erscheinungsjahr: |
2021 |
---|---|
Erschienen: |
2021 |
Enthalten in: |
Zur Gesamtaufnahme - volume:28 |
---|---|
Enthalten in: |
Environmental science and pollution research international - 28(2021), 22 vom: 02. Juni, Seite 28234-28250 |
Sprache: |
Englisch |
---|
Beteiligte Personen: |
Mahana, Abhijeet [VerfasserIn] |
---|
Links: |
---|
Themen: |
Journal Article |
---|
Anmerkungen: |
Date Completed 03.06.2021 Date Revised 03.06.2021 published: Print-Electronic Citation Status MEDLINE |
---|
doi: |
10.1007/s11356-021-12682-7 |
---|
funding: |
|
---|---|
Förderinstitution / Projekttitel: |
|
PPN (Katalog-ID): |
NLM320938395 |
---|
LEADER | 01000naa a22002652 4500 | ||
---|---|---|---|
001 | NLM320938395 | ||
003 | DE-627 | ||
005 | 20231225174738.0 | ||
007 | cr uuu---uuuuu | ||
008 | 231225s2021 xx |||||o 00| ||eng c | ||
024 | 7 | |a 10.1007/s11356-021-12682-7 |2 doi | |
028 | 5 | 2 | |a pubmed24n1069.xml |
035 | |a (DE-627)NLM320938395 | ||
035 | |a (NLM)33533000 | ||
040 | |a DE-627 |b ger |c DE-627 |e rakwb | ||
041 | |a eng | ||
100 | 1 | |a Mahana, Abhijeet |e verfasserin |4 aut | |
245 | 1 | 0 | |a Potential of Scenedesmus-fabricated ZnO nanorods in photocatalytic reduction of methylene blue under direct sunlight |b kinetics and mechanism |
264 | 1 | |c 2021 | |
336 | |a Text |b txt |2 rdacontent | ||
337 | |a ƒaComputermedien |b c |2 rdamedia | ||
338 | |a ƒa Online-Ressource |b cr |2 rdacarrier | ||
500 | |a Date Completed 03.06.2021 | ||
500 | |a Date Revised 03.06.2021 | ||
500 | |a published: Print-Electronic | ||
500 | |a Citation Status MEDLINE | ||
520 | |a Organic synthetic dyes are widely used in several industries; however, their inherent resistance to biodegradation necessitates to investigate alternative methods for the remediation of this class of hazardous substances. In the present study, a green synthesis of ZnO nanorods was achieved in a fast, environment-friendly, and safe microwave process employing algal extract. Different metabolites like sugars, proteins, fatty acids, amino acids, and vitamins present in the algal extract reduced the Zn2+ into ZnO. The XRD analysis showed that the nanostructure was a crystalline hexagonal nanorod having a crystalline size of 27.37 nm. The XPS spectra of ZnO nanorod showed characteristic peaks at binding energy 1043, 1020, 496, 137, 87, and 8 eV corresponding to Zn2p1/2, Zn2p3/2, ZnLMM, Zn3s, Zn3p, Zn3d, respectively. The synthesized ZnO nanorods were in-situ functionalized and showed strong catalytic activity in photoreduction of a model organic dye methylene blue (MB) under direct sunlight irradiation. Synthesized ZnO nanorods showed a complete (100%) reduction of model dye MB from its 10 mg/L aqueous solution. The photocatalytic degradation of MB followed the Michaelis-Menten kinetics. The rate of ZnO-catalyzed photocatalytic degradation depends on the concentrations of ZnO, pH, and sunlight irradiation. The ZnO nanorod-catalyzed photoreduction of MB involves hydroxyl radicals. Algal-mediated and microwave-assisted synthesis provides a scalable source of metal oxide nanoparticles for the remediation of dye-containing wastewaters under natural sunlight. Apart from application in the removal of dyes, ZnO nanorods are excellent material for applications in semiconductors, electronics, optics, bio-imaging, and drug delivery | ||
650 | 4 | |a Journal Article | |
650 | 4 | |a Michaelis-Menten kinetics | |
650 | 4 | |a Microalgae | |
650 | 4 | |a Photodegradation | |
650 | 4 | |a XPS | |
650 | 4 | |a ZnO nanorod | |
650 | 7 | |a Zinc Oxide |2 NLM | |
650 | 7 | |a SOI2LOH54Z |2 NLM | |
650 | 7 | |a Methylene Blue |2 NLM | |
650 | 7 | |a T42P99266K |2 NLM | |
700 | 1 | |a Mehta, Surya Kant |e verfasserin |4 aut | |
773 | 0 | 8 | |i Enthalten in |t Environmental science and pollution research international |d 1994 |g 28(2021), 22 vom: 02. Juni, Seite 28234-28250 |w (DE-627)NLM093849869 |x 1614-7499 |7 nnns |
773 | 1 | 8 | |g volume:28 |g year:2021 |g number:22 |g day:02 |g month:06 |g pages:28234-28250 |
856 | 4 | 0 | |u http://dx.doi.org/10.1007/s11356-021-12682-7 |3 Volltext |
912 | |a GBV_USEFLAG_A | ||
912 | |a GBV_NLM | ||
951 | |a AR | ||
952 | |d 28 |j 2021 |e 22 |b 02 |c 06 |h 28234-28250 |