A Synergy and Struggle of EPR, Magnetometry and NMR : A Case Study of Magnetic Interaction Parameters in a Six-Coordinate Cobalt(II) Complex
Herein, we combine for the first time SQUID magnetometry, cw-EPR, THz-EPR, and paramagnetic NMR spectroscopies to study the magnetic properties of a high-spin cobalt(II) heteroscorpionate complex. Complementary information provided by these methods allowed precise determination of the magnetic interaction parameters, thereby removing the ambiguity inherit to single-method studies. We systematically investigate the extent to which information about the magnetic interaction parameters can be deduced from reduced data sets. The detailed study revealed significant different magnetic properties in solid state and solution. To further exploit the information content of the solution NMR experimental results, we introduce the new concept of reduced paramagnetic shift. It allows for the determination of the magnetic axes and, subsequently, full NMR signal assignment. It is shown that even in complicated cases, in which common NMR analytics (integral intensities, relaxation factors, etc.) fail, it yields robust results.
| Medienart: |
E-Artikel |
|---|
| Erscheinungsjahr: |
2020 |
|---|---|
| Erschienen: |
2020 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:59 |
|---|---|
| Enthalten in: |
Inorganic chemistry - 59(2020), 15 vom: 03. Aug., Seite 10746-10755 |
| Sprache: |
Englisch |
|---|
| Beteiligte Personen: |
Pavlov, Alexander A [VerfasserIn] |
|---|
| Links: |
|---|
| Themen: |
|---|
| Anmerkungen: |
Date Completed 14.08.2020 Date Revised 14.08.2020 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
|---|
| doi: |
10.1021/acs.inorgchem.0c01191 |
|---|
| funding: |
|
|---|---|
| Förderinstitution / Projekttitel: |
|
| PPN (Katalog-ID): |
NLM312493576 |
|---|
| LEADER | 01000naa a22002652 4500 | ||
|---|---|---|---|
| 001 | NLM312493576 | ||
| 003 | DE-627 | ||
| 005 | 20231225144530.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 231225s2020 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1021/acs.inorgchem.0c01191 |2 doi | |
| 028 | 5 | 2 | |a pubmed24n1041.xml |
| 035 | |a (DE-627)NLM312493576 | ||
| 035 | |a (NLM)32672944 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rakwb | ||
| 041 | |a eng | ||
| 100 | 1 | |a Pavlov, Alexander A |e verfasserin |4 aut | |
| 245 | 1 | 2 | |a A Synergy and Struggle of EPR, Magnetometry and NMR |b A Case Study of Magnetic Interaction Parameters in a Six-Coordinate Cobalt(II) Complex |
| 264 | 1 | |c 2020 | |
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a ƒaComputermedien |b c |2 rdamedia | ||
| 338 | |a ƒa Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a Date Completed 14.08.2020 | ||
| 500 | |a Date Revised 14.08.2020 | ||
| 500 | |a published: Print-Electronic | ||
| 500 | |a Citation Status PubMed-not-MEDLINE | ||
| 520 | |a Herein, we combine for the first time SQUID magnetometry, cw-EPR, THz-EPR, and paramagnetic NMR spectroscopies to study the magnetic properties of a high-spin cobalt(II) heteroscorpionate complex. Complementary information provided by these methods allowed precise determination of the magnetic interaction parameters, thereby removing the ambiguity inherit to single-method studies. We systematically investigate the extent to which information about the magnetic interaction parameters can be deduced from reduced data sets. The detailed study revealed significant different magnetic properties in solid state and solution. To further exploit the information content of the solution NMR experimental results, we introduce the new concept of reduced paramagnetic shift. It allows for the determination of the magnetic axes and, subsequently, full NMR signal assignment. It is shown that even in complicated cases, in which common NMR analytics (integral intensities, relaxation factors, etc.) fail, it yields robust results | ||
| 650 | 4 | |a Journal Article | |
| 700 | 1 | |a Nehrkorn, Joscha |e verfasserin |4 aut | |
| 700 | 1 | |a Zubkevich, Sergey V |e verfasserin |4 aut | |
| 700 | 1 | |a Fedin, Matvey V |e verfasserin |4 aut | |
| 700 | 1 | |a Holldack, Karsten |e verfasserin |4 aut | |
| 700 | 1 | |a Schnegg, Alexander |e verfasserin |4 aut | |
| 700 | 1 | |a Novikov, Valentin V |e verfasserin |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Inorganic chemistry |d 1966 |g 59(2020), 15 vom: 03. Aug., Seite 10746-10755 |w (DE-627)NLM110650298 |x 1520-510X |7 nnns |
| 773 | 1 | 8 | |g volume:59 |g year:2020 |g number:15 |g day:03 |g month:08 |g pages:10746-10755 |
| 856 | 4 | 0 | |u http://dx.doi.org/10.1021/acs.inorgchem.0c01191 |3 Volltext |
| 912 | |a GBV_USEFLAG_A | ||
| 912 | |a GBV_NLM | ||
| 951 | |a AR | ||
| 952 | |d 59 |j 2020 |e 15 |b 03 |c 08 |h 10746-10755 | ||