Molecular nanoparticles of cerium dioxide : structure-directing effect of halide ions
The use of halide ions in the synthesis of Ce/O clusters diverts the reaction to two halide-containing products: Cl- gives a new Ce20 nuclearity with both a high 1 : 1 Ce3+ : Ce4+ ratio and a high percentage of (100) facet coverage, whereas F- gives a known Ce6 nuclearity. Both products include bridging halide ions and are thus the first confirmation of non-oxo (OH-/O2-) anion incorporation onto the Ce/O cluster core.
| Medienart: |
E-Artikel |
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| Erscheinungsjahr: |
2020 |
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| Erschienen: |
2020 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:56 |
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| Enthalten in: |
Chemical communications (Cambridge, England) - 56(2020), 40 vom: 19. Mai, Seite 5382-5385 |
| Sprache: |
Englisch |
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| Beteiligte Personen: |
Russell-Webster, Bradley [VerfasserIn] |
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| Anmerkungen: |
Date Revised 19.05.2020 published: Print Citation Status PubMed-not-MEDLINE |
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| doi: |
10.1039/c9cc08419c |
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| funding: |
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| Förderinstitution / Projekttitel: |
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| PPN (Katalog-ID): |
NLM308708709 |
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| 520 | |a The use of halide ions in the synthesis of Ce/O clusters diverts the reaction to two halide-containing products: Cl- gives a new Ce20 nuclearity with both a high 1 : 1 Ce3+ : Ce4+ ratio and a high percentage of (100) facet coverage, whereas F- gives a known Ce6 nuclearity. Both products include bridging halide ions and are thus the first confirmation of non-oxo (OH-/O2-) anion incorporation onto the Ce/O cluster core | ||
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