Removal of organic herbicides from aqueous solution by ionic liquid modified chitosan/metal-organic framework composite

Copyright © 2020. Published by Elsevier B.V..

The novel ILCS/U-X powder materials were fabricated by depositing UiO-66 on ionic liquid modified chitosan, and different doping ratio materials were used to adsorb 2,4-dichlorophenoxyacetic acid in aqueous solution. The samples were characterized by X-ray powder diffraction, Fourier transform infra-red, X-ray photoelectron spectroscopy, Scanning electron microscopy, Brunauer-Emmett-Teller, Barrette-Joyner-Halenda, Thermal gravimetric analyzer, Energy dispersive spectrometer and Zeta potential. Adsorption experiments revealed that temperature and pH have a great influence on adsorption, and all adsorbents have the highest adsorption at low temperature and weak acid. The dependence of ILCS/U-X on pseudo-second order model and Temkin model was observed. Compared to other ratios, the Micro-doped ILCS/U-10 has the largest adsorption capacity and can quickly complete adsorption within 60 min. ILCS/U-10 also has good stability and can be recycled many times. Hydrogen bonding and electrostatic interaction are the two most important forces that dominate adsorption.

Medienart:

E-Artikel

Erscheinungsjahr:

2020

Erschienen:

2020

Enthalten in:

Zur Gesamtaufnahme - volume:149

Enthalten in:

International journal of biological macromolecules - 149(2020) vom: 15. Apr., Seite 882-892

Sprache:

Englisch

Beteiligte Personen:

Huang, Xianglin [VerfasserIn]
Feng, Sheng [VerfasserIn]
Zhu, Guiliang [VerfasserIn]
Zheng, Wei [VerfasserIn]
Shao, Cong [VerfasserIn]
Zhou, Ning [VerfasserIn]
Meng, Qi [VerfasserIn]

Links:

Volltext

Themen:

2,4-D
9012-76-4
Adsorption
Chitosan
Herbicides
Ionic Liquids
Ionic liquid
Journal Article
Metal-Organic Frameworks
Pesticide
UiO-66
Water Pollutants, Chemical

Anmerkungen:

Date Completed 11.12.2020

Date Revised 14.12.2020

published: Print-Electronic

Citation Status MEDLINE

doi:

10.1016/j.ijbiomac.2020.01.165

funding:

Förderinstitution / Projekttitel:

PPN (Katalog-ID):

NLM305600273