Van der Waals Integrated Hybrid POM-Zirconia Flexible Belt-Like Superstructures

© 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim..

A facile one-step solvothermal approach to engineer a van der Waals integrated heteromaterial self-assembled superstructure composed of two structurally distinct species that is polyoxomolybdate and zirconia (POM-ZrO2 ) is reported. Nonclassical aggregation-based self-assembly process grows the superstructure. The introduced POM not only behaves as a catalytically active component of the hybrid structure but also imparts flexibility to the developed POM-ZrO2 superstructures. The material shows high performance toward oxygenation of thioethers as a result of its morphology, composition, and structure. This growing strategy may introduce a viable pathway to the rational design of Van der Waals integrated complex hybrid, catalytically active assemblies with potential applications in different fields.

Medienart:

E-Artikel

Erscheinungsjahr:

2020

Erschienen:

2020

Enthalten in:

Zur Gesamtaufnahme - volume:32

Enthalten in:

Advanced materials (Deerfield Beach, Fla.) - 32(2020), 2 vom: 17. Jan., Seite e1906794

Sprache:

Englisch

Beteiligte Personen:

Akram, Bilal [VerfasserIn]
Ni, Bing [VerfasserIn]
Wang, Xun [VerfasserIn]

Links:

Volltext

Themen:

Hybrid materials
Journal Article
Polyoxometalates
Superstructures
Thioether oxidation
Van der Waals

Anmerkungen:

Date Completed 17.01.2020

Date Revised 01.10.2020

published: Print-Electronic

Citation Status PubMed-not-MEDLINE

doi:

10.1002/adma.201906794

funding:

Förderinstitution / Projekttitel:

PPN (Katalog-ID):

NLM303761040