The low-temperature barium fluoridozirconate variety α-BaZr2F10
The low-temperature triclinic variety α-BaZr2F10 constitutes a new structure type, less symmetrical than the higher-temperature β-variety. It is based on the stacking of double sheets of Zr polyhedra, connecting three different kinds of ZrF7 polyhedra and one ZrF8 polyhedron via vertices and edges, separated by corrugated Ba2+ layers. It is compared to the high-temperature β-variety, directly recrystallizing from barium fluoridozirconate glass, and also to BaTe2F10 and KTe2F9.
| Medienart: |
E-Artikel |
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| Erscheinungsjahr: |
2019 |
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| Erschienen: |
2019 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:75 |
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| Enthalten in: |
Acta crystallographica. Section C, Structural chemistry - 75(2019), Pt 11 vom: 01. Nov., Seite 1482-1487 |
| Sprache: |
Englisch |
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| Beteiligte Personen: |
Laval, Jean Paul [VerfasserIn] |
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| Links: |
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| Themen: |
BaZr2F10 |
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| Anmerkungen: |
Date Completed 13.11.2019 Date Revised 13.11.2019 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
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| doi: |
10.1107/S205322961901297X |
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| funding: |
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| Förderinstitution / Projekttitel: |
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| PPN (Katalog-ID): |
NLM302909575 |
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| 520 | |a The low-temperature triclinic variety α-BaZr2F10 constitutes a new structure type, less symmetrical than the higher-temperature β-variety. It is based on the stacking of double sheets of Zr polyhedra, connecting three different kinds of ZrF7 polyhedra and one ZrF8 polyhedron via vertices and edges, separated by corrugated Ba2+ layers. It is compared to the high-temperature β-variety, directly recrystallizing from barium fluoridozirconate glass, and also to BaTe2F10 and KTe2F9 | ||
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| 650 | 4 | |a crystal structure | |
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| 650 | 4 | |a zirconium fluoride | |
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