Cesium Lead Inorganic Solar Cell with Efficiency beyond 18% via Reduced Charge Recombination
© 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim..
Cesium-based inorganic perovskite solar cells (PSCs) are promising due to their potential for improving device stability. However, the power conversion efficiency of the inorganic PSCs is still low compared with the hybrid PSCs due to the large open-circuit voltage (VOC ) loss possibly caused by charge recombination. The use of an insulated shunt-blocking layer lithium fluoride on electron transport layer SnO2 for better energy level alignment with the conduction band minimum of the CsPbI3- x Brx and also for interface defect passivation is reported. In addition, by incorporating lead chloride in CsPbI3- x Brx precursor, the perovskite film crystallinity is significantly enhanced and the charge recombination in perovksite is suppressed. As a result, optimized CsPbI3- x Brx PSCs with a band gap of 1.77 eV exhibit excellent performance with the best VOC as high as 1.25 V and an efficiency of 18.64%. Meanwhile, a high photostability with a less than 6% efficiency drop is achieved for CsPbI3- x Brx PSCs under continuous 1 sun equivalent illumination over 1000 h.
| Errataetall: |
ErratumIn: Adv Mater. 2021 Mar;33(10):e2100344. - PMID 33686749 |
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| Medienart: |
E-Artikel |
| Erscheinungsjahr: |
2019 |
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| Erschienen: |
2019 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:31 |
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| Enthalten in: |
Advanced materials (Deerfield Beach, Fla.) - 31(2019), 49 vom: 06. Dez., Seite e1905143 |
| Sprache: |
Englisch |
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| Beteiligte Personen: |
Ye, Qiufeng [VerfasserIn] |
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| Links: |
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| Themen: |
Inorganic perovskite solar cells |
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| Anmerkungen: |
Date Completed 09.12.2019 Date Revised 09.03.2021 published: Print-Electronic ErratumIn: Adv Mater. 2021 Mar;33(10):e2100344. - PMID 33686749 Citation Status PubMed-not-MEDLINE |
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| doi: |
10.1002/adma.201905143 |
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| funding: |
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| Förderinstitution / Projekttitel: |
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| 500 | |a Citation Status PubMed-not-MEDLINE | ||
| 520 | |a © 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. | ||
| 520 | |a Cesium-based inorganic perovskite solar cells (PSCs) are promising due to their potential for improving device stability. However, the power conversion efficiency of the inorganic PSCs is still low compared with the hybrid PSCs due to the large open-circuit voltage (VOC ) loss possibly caused by charge recombination. The use of an insulated shunt-blocking layer lithium fluoride on electron transport layer SnO2 for better energy level alignment with the conduction band minimum of the CsPbI3- x Brx and also for interface defect passivation is reported. In addition, by incorporating lead chloride in CsPbI3- x Brx precursor, the perovskite film crystallinity is significantly enhanced and the charge recombination in perovksite is suppressed. As a result, optimized CsPbI3- x Brx PSCs with a band gap of 1.77 eV exhibit excellent performance with the best VOC as high as 1.25 V and an efficiency of 18.64%. Meanwhile, a high photostability with a less than 6% efficiency drop is achieved for CsPbI3- x Brx PSCs under continuous 1 sun equivalent illumination over 1000 h | ||
| 650 | 4 | |a Journal Article | |
| 650 | 4 | |a VOC loss | |
| 650 | 4 | |a inorganic perovskite solar cells | |
| 650 | 4 | |a recombination defects | |
| 700 | 1 | |a Zhao, Yang |e verfasserin |4 aut | |
| 700 | 1 | |a Mu, Shaiqiang |e verfasserin |4 aut | |
| 700 | 1 | |a Ma, Fei |e verfasserin |4 aut | |
| 700 | 1 | |a Gao, Feng |e verfasserin |4 aut | |
| 700 | 1 | |a Chu, Zema |e verfasserin |4 aut | |
| 700 | 1 | |a Yin, Zhigang |e verfasserin |4 aut | |
| 700 | 1 | |a Gao, Pingqi |e verfasserin |4 aut | |
| 700 | 1 | |a Zhang, Xingwang |e verfasserin |4 aut | |
| 700 | 1 | |a You, Jingbi |e verfasserin |4 aut | |
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