Dataset of polyoxometalate-assisted N-heterocyclic carbene gold(I) complexes
The present paper is the Supplemental materials for our original paper entitled "highly active, homogeneous catalysis by polyoxometalate-assisted N-heterocyclic carbene gold(I) complexes for hydration of diphenylacetylene. The present article refers to the preparations of several monomeric, N-heterocyclic (NHC) carbene/carboxylate (RS-pyrrld)/gold(I) complexes, [Au(RS-pyrrld)(NHC)] (NHC = IMes (6), BIPr (7), IF3 (8), ItBu (9)), which were used for homogenous catalysis of the hydration reaction of diphenylacetylene to afford deoxybenzoin. The article also includes the preparations of the precursor complexes, [AuCl(NHC)] (NHC = IPr, IMes, BIPr, IF3, ItBu), and novel X-ray crystallography of the separately prepared [Au(IPr)(H2O)]3[α-PW12O40]·7Et2O (2), summary of crystal data of (2), and selected bond distances (Å) and angles (deg) of (2). Also presented are Cartesian coordinates of the optimized structures in the quantum-mechanical calculations.
| Medienart: |
E-Artikel |
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| Erscheinungsjahr: |
2019 |
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| Erschienen: |
2019 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:25 |
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| Enthalten in: |
Data in brief - 25(2019) vom: 15. Aug., Seite 104002 |
| Sprache: |
Englisch |
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| Beteiligte Personen: |
Nomiya, Kenji [VerfasserIn] |
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| Links: |
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| Themen: |
Gold(I) complex |
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| Anmerkungen: |
Date Revised 29.09.2020 published: Electronic-eCollection Citation Status PubMed-not-MEDLINE |
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| doi: |
10.1016/j.dib.2019.104002 |
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| funding: |
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| Förderinstitution / Projekttitel: |
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| PPN (Katalog-ID): |
NLM298154455 |
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| 500 | |a Date Revised 29.09.2020 | ||
| 500 | |a published: Electronic-eCollection | ||
| 500 | |a Citation Status PubMed-not-MEDLINE | ||
| 520 | |a The present paper is the Supplemental materials for our original paper entitled "highly active, homogeneous catalysis by polyoxometalate-assisted N-heterocyclic carbene gold(I) complexes for hydration of diphenylacetylene. The present article refers to the preparations of several monomeric, N-heterocyclic (NHC) carbene/carboxylate (RS-pyrrld)/gold(I) complexes, [Au(RS-pyrrld)(NHC)] (NHC = IMes (6), BIPr (7), IF3 (8), ItBu (9)), which were used for homogenous catalysis of the hydration reaction of diphenylacetylene to afford deoxybenzoin. The article also includes the preparations of the precursor complexes, [AuCl(NHC)] (NHC = IPr, IMes, BIPr, IF3, ItBu), and novel X-ray crystallography of the separately prepared [Au(IPr)(H2O)]3[α-PW12O40]·7Et2O (2), summary of crystal data of (2), and selected bond distances (Å) and angles (deg) of (2). Also presented are Cartesian coordinates of the optimized structures in the quantum-mechanical calculations | ||
| 650 | 4 | |a Journal Article | |
| 650 | 4 | |a Gold(I) complex | |
| 650 | 4 | |a Homogeneous catalysis | |
| 650 | 4 | |a Hydration of diphenylacetylene | |
| 650 | 4 | |a N-Heterocyclic carbene ligand | |
| 650 | 4 | |a Polyoxometalate | |
| 700 | 1 | |a Murata, Yuichi |e verfasserin |4 aut | |
| 700 | 1 | |a Iwasaki, Yuta |e verfasserin |4 aut | |
| 700 | 1 | |a Arai, Hidekazu |e verfasserin |4 aut | |
| 700 | 1 | |a Yoshida, Takuya |e verfasserin |4 aut | |
| 700 | 1 | |a Kasuga, Noriko Chikaraishi |e verfasserin |4 aut | |
| 700 | 1 | |a Matsubara, Toshiaki |e verfasserin |4 aut | |
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