Core-shell Fe3O4Au nanocomposite as dual-functional optical probe and potential removal system for arsenic (III) from Water
Copyright © 2019 Elsevier B.V. All rights reserved..
We report for the very first time, development of a dual functional nanocomposite to perform as an optical probe as well as removal system for As(III) from ground water. Upon suitable thiolation using dithiothreitol (DTT), the Fe3O4(core)-Au(shell) nanocomposite (DTT-Fe3O4Au) has been fabricated that can detect As(III) in aqueous solution with significantly low limit of detection and holds potential for selective removal of As(III) from water owing to its magnetic core. Due to high affinity of -SH groups for As(III), the nanoparticles undergo aggregation in the presence of As(III), resulting in a significant decrease in absorbance, yielding the limit of detection (LOD) as 0.86 ppb, which is much lower than the World Health Organisation (WHO) recommended threshold value of 10 ppb. UV-vis spectroscopy in conjunction with dynamic light scattering and electron microscopy techniques have further elaborated the detailed interaction between As(III) and DTT-Fe3O4@Au nanocomposite regarding their size dynamics and solution behaviour during the interaction. Moreover, ca.70% removal of As(III) from aqueous solution by DTT-Fe3O4@Au has been observed by ICP-MS measurement strengthening the potential of this nanocomposite as a dual-functional probe and filter.
| Medienart: |
E-Artikel |
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| Erscheinungsjahr: |
2019 |
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| Erschienen: |
2019 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:375 |
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| Enthalten in: |
Journal of hazardous materials - 375(2019) vom: 05. Aug., Seite 216-223 |
| Sprache: |
Englisch |
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| Beteiligte Personen: |
Banerjee, Swagata [VerfasserIn] |
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| Links: |
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| Themen: |
Arsenic |
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| Anmerkungen: |
Date Completed 27.02.2020 Date Revised 27.02.2020 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
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| doi: |
10.1016/j.jhazmat.2019.04.085 |
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| funding: |
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| Förderinstitution / Projekttitel: |
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| PPN (Katalog-ID): |
NLM296947075 |
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| 500 | |a published: Print-Electronic | ||
| 500 | |a Citation Status PubMed-not-MEDLINE | ||
| 520 | |a Copyright © 2019 Elsevier B.V. All rights reserved. | ||
| 520 | |a We report for the very first time, development of a dual functional nanocomposite to perform as an optical probe as well as removal system for As(III) from ground water. Upon suitable thiolation using dithiothreitol (DTT), the Fe3O4(core)-Au(shell) nanocomposite (DTT-Fe3O4Au) has been fabricated that can detect As(III) in aqueous solution with significantly low limit of detection and holds potential for selective removal of As(III) from water owing to its magnetic core. Due to high affinity of -SH groups for As(III), the nanoparticles undergo aggregation in the presence of As(III), resulting in a significant decrease in absorbance, yielding the limit of detection (LOD) as 0.86 ppb, which is much lower than the World Health Organisation (WHO) recommended threshold value of 10 ppb. UV-vis spectroscopy in conjunction with dynamic light scattering and electron microscopy techniques have further elaborated the detailed interaction between As(III) and DTT-Fe3O4@Au nanocomposite regarding their size dynamics and solution behaviour during the interaction. Moreover, ca.70% removal of As(III) from aqueous solution by DTT-Fe3O4@Au has been observed by ICP-MS measurement strengthening the potential of this nanocomposite as a dual-functional probe and filter | ||
| 650 | 4 | |a Journal Article | |
| 650 | 4 | |a Research Support, Non-U.S. Gov't | |
| 650 | 4 | |a Arsenic | |
| 650 | 4 | |a Arsenic removal | |
| 650 | 4 | |a As(III) detection | |
| 650 | 4 | |a Fe(3)O(4) | |
| 650 | 4 | |a Gold nanoparticle | |
| 700 | 1 | |a Kumar, N Pavan |e verfasserin |4 aut | |
| 700 | 1 | |a Srinivas, Adiraj |e verfasserin |4 aut | |
| 700 | 1 | |a Roy, Shibsekhar |e verfasserin |4 aut | |
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