Dehydrogenative β-Arylation of Saturated Aldehydes Using Transient Directing Groups
An unprecedented cross-dehydrogenative-coupling (CDC) reaction of saturated aldehyde β-C-H with arenes to form cinnamaldehydes via the cleavages of four C-H bonds has been developed. The reaction possesses complete E-stereoselectivity for the C═C double bond. The protocol is featured by atom and step economy, mild reaction conditions, and convenient operation.
| Medienart: |
E-Artikel |
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| Erscheinungsjahr: |
2019 |
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| Erschienen: |
2019 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:21 |
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| Enthalten in: |
Organic letters - 21(2019), 8 vom: 19. Apr., Seite 2731-2735 |
| Sprache: |
Englisch |
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| Beteiligte Personen: |
Zhang, Xing-Long [VerfasserIn] |
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| Links: |
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| Themen: |
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| Anmerkungen: |
Date Revised 20.11.2019 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
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| doi: |
10.1021/acs.orglett.9b00695 |
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| funding: |
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| Förderinstitution / Projekttitel: |
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| PPN (Katalog-ID): |
NLM295392622 |
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| 520 | |a An unprecedented cross-dehydrogenative-coupling (CDC) reaction of saturated aldehyde β-C-H with arenes to form cinnamaldehydes via the cleavages of four C-H bonds has been developed. The reaction possesses complete E-stereoselectivity for the C═C double bond. The protocol is featured by atom and step economy, mild reaction conditions, and convenient operation | ||
| 650 | 4 | |a Journal Article | |
| 650 | 4 | |a Research Support, Non-U.S. Gov't | |
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| 700 | 1 | |a Zhu, Xue-Qing |e verfasserin |4 aut | |
| 700 | 1 | |a Guo, Rui-Li |e verfasserin |4 aut | |
| 700 | 1 | |a Gao, Ya-Ru |e verfasserin |4 aut | |
| 700 | 1 | |a Wang, Yong-Qiang |e verfasserin |4 aut | |
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