Bimetallic nickel-cobalt hydrides in H2 activation and catalytic proton reduction
The synergism of the electronic properties of nickel and cobalt enables bimetallic NiCo complexes to process H2. The nickel-cobalt hydride [(dppe)Ni(pdt)(H)CoCp*]+ ([1H]+ ) arising from protonation of the reduced state 1 was found to be an efficient electrocatalyst for H2 evolution with Cl2CHCOOH, and the oxidized [Ni(ii)Co(iii)]2+ form is capable of activating H2 to produce [1H]+ . The features of stereodynamics, acid-base properties, redox chemistry and reactivity of these bimetallic NiCo complexes in processing H2 are potentially related to the active site of [NiFe]-H2ases.
| Medienart: |
E-Artikel |
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| Erscheinungsjahr: |
2019 |
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| Erschienen: |
2019 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:10 |
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| Enthalten in: |
Chemical science - 10(2019), 3 vom: 21. Jan., Seite 761-767 |
| Sprache: |
Englisch |
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| Beteiligte Personen: |
Chu, Xiaoxiao [VerfasserIn] |
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| Links: |
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| Themen: |
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| Anmerkungen: |
Date Revised 05.10.2023 published: Electronic-eCollection Citation Status PubMed-not-MEDLINE |
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| doi: |
10.1039/c8sc04346a |
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| funding: |
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| Förderinstitution / Projekttitel: |
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| PPN (Katalog-ID): |
NLM29371911X |
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| 245 | 1 | 0 | |a Bimetallic nickel-cobalt hydrides in H2 activation and catalytic proton reduction |
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| 500 | |a Date Revised 05.10.2023 | ||
| 500 | |a published: Electronic-eCollection | ||
| 500 | |a Citation Status PubMed-not-MEDLINE | ||
| 520 | |a The synergism of the electronic properties of nickel and cobalt enables bimetallic NiCo complexes to process H2. The nickel-cobalt hydride [(dppe)Ni(pdt)(H)CoCp*]+ ([1H]+ ) arising from protonation of the reduced state 1 was found to be an efficient electrocatalyst for H2 evolution with Cl2CHCOOH, and the oxidized [Ni(ii)Co(iii)]2+ form is capable of activating H2 to produce [1H]+ . The features of stereodynamics, acid-base properties, redox chemistry and reactivity of these bimetallic NiCo complexes in processing H2 are potentially related to the active site of [NiFe]-H2ases | ||
| 650 | 4 | |a Journal Article | |
| 700 | 1 | |a Jin, Jihao |e verfasserin |4 aut | |
| 700 | 1 | |a Ming, Bangrong |e verfasserin |4 aut | |
| 700 | 1 | |a Pang, Maofu |e verfasserin |4 aut | |
| 700 | 1 | |a Yu, Xin |e verfasserin |4 aut | |
| 700 | 1 | |a Tung, Chen-Ho |e verfasserin |4 aut | |
| 700 | 1 | |a Wang, Wenguang |e verfasserin |4 aut | |
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