Sequential X-ray-Induced Single-Crystal to Single-Crystal Transformation followed by Topotactic Reduction in a Potassium Crown Ether Complex of Tetrachloroaurate(III)

During data collection, the unreported potassium crown ether salt [K(18-crown-6][AuCl4] undergoes a sequential X-ray-induced and irreversible single-crystal to single-crystal transformation from P1̅ to C2/ c followed by a topotactic reduction to crystalline [K(18-crown-6][AuCl2] within the same C2/ c space group.

Medienart:

E-Artikel

Erscheinungsjahr:

2018

Erschienen:

2018

Enthalten in:

Zur Gesamtaufnahme - volume:57

Enthalten in:

Inorganic chemistry - 57(2018), 21 vom: 05. Nov., Seite 13524-13532

Sprache:

Englisch

Beteiligte Personen:

Sethi, Navpreet K [VerfasserIn]
Whitwood, Adrian C [VerfasserIn]
Bruce, Duncan W [VerfasserIn]

Links:

Volltext

Themen:

Journal Article

Anmerkungen:

Date Completed 05.11.2018

Date Revised 05.11.2018

published: Print-Electronic

Citation Status PubMed-not-MEDLINE

doi:

10.1021/acs.inorgchem.8b02130

funding:

Förderinstitution / Projekttitel:

PPN (Katalog-ID):

NLM289243572