N,N-Disubstituted-N'-acylthioureas as modular ligands for deposition of transition metal sulfides

First row transition metal complexes (Ni, Co, Cu, Zn) with N,N-disubstituted-N'-acylthiourea ligands have been synthesized and characterized. Bis(N,N-diisopropyl-N'-cinnamoylthiourea)nickel was found to have the lowest onset temperature for thermal decomposition. Thin film deposition of Ni, Co, and Zn sulfides by aerosol assisted chemical vapor deposition from their respective N,N-diisopropyl-N'-cinnamoylthiourea complexes at 350 °C has been demonstrated.

Medienart:

E-Artikel

Erscheinungsjahr:

2018

Erschienen:

2018

Enthalten in:

Zur Gesamtaufnahme - volume:47

Enthalten in:

Dalton transactions (Cambridge, England : 2003) - 47(2018), 8 vom: 20. Feb., Seite 2719-2726

Sprache:

Englisch

Beteiligte Personen:

Ali, Zahra [VerfasserIn]
Richey, Nathaniel E [VerfasserIn]
Bock, Duane C [VerfasserIn]
Abboud, Khalil A [VerfasserIn]
Akhtar, Javeed [VerfasserIn]
Sher, Muhammad [VerfasserIn]
McElwee-White, Lisa [VerfasserIn]

Links:

Volltext

Themen:

Journal Article

Anmerkungen:

Date Completed 23.03.2018

Date Revised 20.02.2019

published: Print

Citation Status PubMed-not-MEDLINE

doi:

10.1039/c7dt04860b

funding:

Förderinstitution / Projekttitel:

PPN (Katalog-ID):

NLM280713894