Silver(I)-Catalyzed C4-H Amination of 1-Naphthylamine Derivatives with Azodicarboxylates

A simple and efficient protocol for silver(I)-catalyzed picolinamide directed C4-H amination of 1-naphthylamine derivatives with readily available azodicarboxylates has been developed, demonstrating a new approach to 1,4-naphthalenediamine derivatives in high yields. Note that this reaction system could proceed under external-oxidant- and additive-free conditions (only requires 5 mol % of AgOAc as the catalyst in acetone).

Medienart:

E-Artikel

Erscheinungsjahr:

2018

Erschienen:

2018

Enthalten in:

Zur Gesamtaufnahme - volume:20

Enthalten in:

Organic letters - 20(2018), 3 vom: 02. Feb., Seite 620-623

Sprache:

Englisch

Beteiligte Personen:

Zhu, Hongmei [VerfasserIn]
Sun, Suyan [VerfasserIn]
Qiao, Huijie [VerfasserIn]
Yang, Fan [VerfasserIn]
Kang, Jianxun [VerfasserIn]
Wu, Yusheng [VerfasserIn]
Wu, Yangjie [VerfasserIn]

Links:

Volltext

Themen:

Journal Article
Research Support, Non-U.S. Gov't

Anmerkungen:

Date Completed 27.06.2018

Date Revised 27.06.2018

published: Print-Electronic

Citation Status PubMed-not-MEDLINE

doi:

10.1021/acs.orglett.7b03749

funding:

Förderinstitution / Projekttitel:

PPN (Katalog-ID):

NLM280219458