Palladium-catalyzed oxidative arylacetoxylation of alkenes : synthesis of indole and indoline derivatives
A method for the oxidative arylacetoxylation of alkenes has been developed to synthesize indole and indoline derivatives from readily accessible substrates. The cinnamyl tethered anilines with picolinamide as a directing group provided 3-substituted indoles via intramolecular oxidative arylacetoxylation, and the 2-methyl substituted cinnamyl anilines furnished indoline derivatives with 3-position quaternary stereocenters in good to excellent yields via sequential intramolecular oxidative arylacetoxylation, hydrolysis and oxidation steps.
| Medienart: |
E-Artikel |
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| Erscheinungsjahr: |
2017 |
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| Erschienen: |
2017 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:53 |
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| Enthalten in: |
Chemical communications (Cambridge, England) - 53(2017), 81 vom: 18. Okt., Seite 11205-11208 |
| Sprache: |
Englisch |
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| Beteiligte Personen: |
Karnakanti, Shuklachary [VerfasserIn] |
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| Links: |
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| Themen: |
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| Anmerkungen: |
Date Completed 02.03.2018 Date Revised 02.03.2018 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
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| doi: |
10.1039/c7cc06448a |
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| funding: |
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| Förderinstitution / Projekttitel: |
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| PPN (Katalog-ID): |
NLM276265068 |
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| 100 | 1 | |a Karnakanti, Shuklachary |e verfasserin |4 aut | |
| 245 | 1 | 0 | |a Palladium-catalyzed oxidative arylacetoxylation of alkenes |b synthesis of indole and indoline derivatives |
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| 500 | |a published: Print-Electronic | ||
| 500 | |a Citation Status PubMed-not-MEDLINE | ||
| 520 | |a A method for the oxidative arylacetoxylation of alkenes has been developed to synthesize indole and indoline derivatives from readily accessible substrates. The cinnamyl tethered anilines with picolinamide as a directing group provided 3-substituted indoles via intramolecular oxidative arylacetoxylation, and the 2-methyl substituted cinnamyl anilines furnished indoline derivatives with 3-position quaternary stereocenters in good to excellent yields via sequential intramolecular oxidative arylacetoxylation, hydrolysis and oxidation steps | ||
| 650 | 4 | |a Journal Article | |
| 700 | 1 | |a Zang, Zhong-Lin |e verfasserin |4 aut | |
| 700 | 1 | |a Zhao, Sheng |e verfasserin |4 aut | |
| 700 | 1 | |a Shao, Pan-Lin |e verfasserin |4 aut | |
| 700 | 1 | |a Hu, Ping |e verfasserin |4 aut | |
| 700 | 1 | |a He, Yun |e verfasserin |4 aut | |
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