Synthesis of Silicon and Germanium-Containing Heterosumanenes via Rhodium-Catalyzed Cyclodehydrogenation of Silicon/Germanium-Hydrogen and Carbon-Hydrogen Bonds
A three-step synthesis of C3-symmetric trisilasumanene and trigermasumanene, heteroanalogues of the π-bowl sumanene, was achieved using a threefold rhodium-catalyzed cyclodehydrogenation of Si/Ge-H and C-H bonds as the key step. Trigermasumanene was proven to adopt a planar geometry by single crystal X-ray diffraction for the first time. The optical properties were also investigated by UV-vis and fluorescence spectroscopy.
| Medienart: |
E-Artikel |
|---|
| Erscheinungsjahr: |
2017 |
|---|---|
| Erschienen: |
2017 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:19 |
|---|---|
| Enthalten in: |
Organic letters - 19(2017), 17 vom: 01. Sept., Seite 4628-4631 |
| Sprache: |
Englisch |
|---|
| Beteiligte Personen: |
Zhou, Dandan [VerfasserIn] |
|---|
| Links: |
|---|
| Themen: |
|---|
| Anmerkungen: |
Date Completed 13.06.2018 Date Revised 13.06.2018 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
|---|
| doi: |
10.1021/acs.orglett.7b02254 |
|---|
| funding: |
|
|---|---|
| Förderinstitution / Projekttitel: |
|
| PPN (Katalog-ID): |
NLM275051129 |
|---|
| LEADER | 01000naa a22002652 4500 | ||
|---|---|---|---|
| 001 | NLM275051129 | ||
| 003 | DE-627 | ||
| 005 | 20231225004815.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 231225s2017 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1021/acs.orglett.7b02254 |2 doi | |
| 028 | 5 | 2 | |a pubmed24n0916.xml |
| 035 | |a (DE-627)NLM275051129 | ||
| 035 | |a (NLM)28832161 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rakwb | ||
| 041 | |a eng | ||
| 100 | 1 | |a Zhou, Dandan |e verfasserin |4 aut | |
| 245 | 1 | 0 | |a Synthesis of Silicon and Germanium-Containing Heterosumanenes via Rhodium-Catalyzed Cyclodehydrogenation of Silicon/Germanium-Hydrogen and Carbon-Hydrogen Bonds |
| 264 | 1 | |c 2017 | |
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a ƒaComputermedien |b c |2 rdamedia | ||
| 338 | |a ƒa Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a Date Completed 13.06.2018 | ||
| 500 | |a Date Revised 13.06.2018 | ||
| 500 | |a published: Print-Electronic | ||
| 500 | |a Citation Status PubMed-not-MEDLINE | ||
| 520 | |a A three-step synthesis of C3-symmetric trisilasumanene and trigermasumanene, heteroanalogues of the π-bowl sumanene, was achieved using a threefold rhodium-catalyzed cyclodehydrogenation of Si/Ge-H and C-H bonds as the key step. Trigermasumanene was proven to adopt a planar geometry by single crystal X-ray diffraction for the first time. The optical properties were also investigated by UV-vis and fluorescence spectroscopy | ||
| 650 | 4 | |a Journal Article | |
| 650 | 4 | |a Research Support, Non-U.S. Gov't | |
| 700 | 1 | |a Gao, Ya |e verfasserin |4 aut | |
| 700 | 1 | |a Liu, Bingxin |e verfasserin |4 aut | |
| 700 | 1 | |a Tan, Qitao |e verfasserin |4 aut | |
| 700 | 1 | |a Xu, Bin |e verfasserin |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Organic letters |d 1999 |g 19(2017), 17 vom: 01. Sept., Seite 4628-4631 |w (DE-627)NLM106817639 |x 1523-7052 |7 nnns |
| 773 | 1 | 8 | |g volume:19 |g year:2017 |g number:17 |g day:01 |g month:09 |g pages:4628-4631 |
| 856 | 4 | 0 | |u http://dx.doi.org/10.1021/acs.orglett.7b02254 |3 Volltext |
| 912 | |a GBV_USEFLAG_A | ||
| 912 | |a GBV_NLM | ||
| 951 | |a AR | ||
| 952 | |d 19 |j 2017 |e 17 |b 01 |c 09 |h 4628-4631 | ||