Benzotrifuran (BTFuran) : a building block for π-conjugated systems
Reported here is the first synthesis, X-ray crystal structure, and derivatization of benzotrifuran (BTFuran). Single crystal X-ray analysis of BTFuran shows a tight hexagonal packing stabilized by π-stacking interactions and C-H···O contacts. α-Lithiation of BTFuran enables the preparation of reactive intermediates suitable for cross-coupling reactions, allowing access to representative BTFuran-containing π-conjugated systems.
| Medienart: |
E-Artikel |
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| Erscheinungsjahr: |
2017 |
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| Erschienen: |
2017 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:53 |
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| Enthalten in: |
Chemical communications (Cambridge, England) - 53(2017), 69 vom: 24. Aug., Seite 9590-9593 |
| Sprache: |
Englisch |
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| Beteiligte Personen: |
Ferreira, Renan B [VerfasserIn] |
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| Links: |
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| Anmerkungen: |
Date Completed 05.03.2018 Date Revised 05.03.2018 published: Print Citation Status PubMed-not-MEDLINE |
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| doi: |
10.1039/c7cc04505k |
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| funding: |
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| Förderinstitution / Projekttitel: |
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| PPN (Katalog-ID): |
NLM274827182 |
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| 500 | |a Citation Status PubMed-not-MEDLINE | ||
| 520 | |a Reported here is the first synthesis, X-ray crystal structure, and derivatization of benzotrifuran (BTFuran). Single crystal X-ray analysis of BTFuran shows a tight hexagonal packing stabilized by π-stacking interactions and C-H···O contacts. α-Lithiation of BTFuran enables the preparation of reactive intermediates suitable for cross-coupling reactions, allowing access to representative BTFuran-containing π-conjugated systems | ||
| 650 | 4 | |a Journal Article | |
| 700 | 1 | |a Figueroa, Jose M |e verfasserin |4 aut | |
| 700 | 1 | |a Fagnani, Danielle E |e verfasserin |4 aut | |
| 700 | 1 | |a Abboud, Khalil A |e verfasserin |4 aut | |
| 700 | 1 | |a Castellano, Ronald K |e verfasserin |4 aut | |
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