Metal-Free Oxidative C-C Bond Functionalization of Methylenecyclopropanes with Ethers Leading to 2-Substituted 3,4-Dihydronaphthalenes
A novel metal-free oxidative ring-opening/cyclization of methylenecyclopropanes with ethers was established for the synthesis of diverse 2-substituted 3,4-dihydronaphthalenes with high selectivity and efficiency. This oxidative cyclization is achieved by C(sp3)-H functionalization, ring-opening, and cyclization, and this method represents a new example of methylenecyclopropane oxidative cyclization with an aromatic carbon and a C(sp3)-H bond by simultaneously forming two new carbon-carbon bonds.
| Medienart: |
E-Artikel |
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| Erscheinungsjahr: |
2017 |
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| Erschienen: |
2017 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:82 |
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| Enthalten in: |
The Journal of organic chemistry - 82(2017), 14 vom: 21. Juli, Seite 7394-7401 |
| Sprache: |
Englisch |
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| Beteiligte Personen: |
Liu, Yu [VerfasserIn] |
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| Links: |
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| Themen: |
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| Anmerkungen: |
Date Completed 28.05.2018 Date Revised 28.05.2018 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
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| doi: |
10.1021/acs.joc.7b00970 |
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| funding: |
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| Förderinstitution / Projekttitel: |
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| PPN (Katalog-ID): |
NLM273097601 |
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| 245 | 1 | 0 | |a Metal-Free Oxidative C-C Bond Functionalization of Methylenecyclopropanes with Ethers Leading to 2-Substituted 3,4-Dihydronaphthalenes |
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| 500 | |a Date Completed 28.05.2018 | ||
| 500 | |a Date Revised 28.05.2018 | ||
| 500 | |a published: Print-Electronic | ||
| 500 | |a Citation Status PubMed-not-MEDLINE | ||
| 520 | |a A novel metal-free oxidative ring-opening/cyclization of methylenecyclopropanes with ethers was established for the synthesis of diverse 2-substituted 3,4-dihydronaphthalenes with high selectivity and efficiency. This oxidative cyclization is achieved by C(sp3)-H functionalization, ring-opening, and cyclization, and this method represents a new example of methylenecyclopropane oxidative cyclization with an aromatic carbon and a C(sp3)-H bond by simultaneously forming two new carbon-carbon bonds | ||
| 650 | 4 | |a Journal Article | |
| 650 | 4 | |a Research Support, Non-U.S. Gov't | |
| 700 | 1 | |a Wang, Qiao-Lin |e verfasserin |4 aut | |
| 700 | 1 | |a Zhou, Cong-Shan |e verfasserin |4 aut | |
| 700 | 1 | |a Xiong, Bi-Quan |e verfasserin |4 aut | |
| 700 | 1 | |a Zhang, Pan-Liang |e verfasserin |4 aut | |
| 700 | 1 | |a Yang, Chang-An |e verfasserin |4 aut | |
| 700 | 1 | |a Tang, Ke-Wen |e verfasserin |4 aut | |
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