Strong Electromagnetic Wave Response Derived from the Construction of Dielectric/Magnetic Media Heterostructure and Multiple Interfaces

A novel yolk-shell structure of cobalt nanoparticle embedded nanoporous carboncarbonyl iron (Co/NPC@Void@CI) was synthesized via metal organic chemical vapor deposition (MOCVD) and subsequent calcination treatment. The in situ generation of void layer, which originated from the shrink of a Co-based zeolitic imidazolate framework (ZIF-67) during carbonization, embodies distinct advantage compared to the conventional template method. Thanks to the introduction of custom-designed dielectric/magnetic media heterostructure and multiple interfaces, the composites filled with 40 wt % of Co/NPC@Void@CI samples in paraffin exhibit a maximum reflection loss of -49.2 dB at 2.2 mm; importantly, a broad absorption bandwidth (RL < -10 dB) of 6.72 GHz can be obtained, which covers more than one-third of the whole frequency region from 10.56 to 17.28 GHz. This study not only develops the application of carbonyl iron as a high-efficiency light absorber but also initiates a fire-new avenue for artificially designed heterostructures with target functionalities.

Medienart:

E-Artikel

Erscheinungsjahr:

2017

Erschienen:

2017

Enthalten in:

Zur Gesamtaufnahme - volume:9

Enthalten in:

ACS applied materials & interfaces - 9(2017), 11 vom: 22. März, Seite 9964-9974

Sprache:

Englisch

Beteiligte Personen:

Quan, Bin [VerfasserIn]
Liang, Xiaohui [VerfasserIn]
Ji, Guangbin [VerfasserIn]
Ma, Jianna [VerfasserIn]
Ouyang, Peiyi [VerfasserIn]
Gong, He [VerfasserIn]
Xu, Guoyue [VerfasserIn]
Du, Youwei [VerfasserIn]

Links:

Volltext

Themen:

Carbonyl iron
Electromagnetic wave absorbing
Heterostructure
Journal Article
Multiple interfaces
Yolk−shell

Anmerkungen:

Date Completed 30.07.2018

Date Revised 30.07.2018

published: Print-Electronic

Citation Status PubMed-not-MEDLINE

doi:

10.1021/acsami.6b15788

funding:

Förderinstitution / Projekttitel:

PPN (Katalog-ID):

NLM269398937