Crystal structure of bis-(1-ethyl-pyridinium) dioxonium hexa-cyanidoferrate(II)
The title compound, (C7H10N)2(H3O)2[Fe(CN)6] or (Etpy)2(H3O)2[Fe(CN)6] (Etpy+ is 1-ethyl-pyridinium), crystallizes in the space group Pnnm. The FeII atom of the [Fe(CN)6]4- anion lies on a site with site symmetry ..2/m, and has an octa-hedral coordination sphere defined by six cyanido ligands. Both the Etpy+ and the oxonium cations are located on a mirror plane. In the crystal, electron-donor anions of [Fe(CN)6]4- and electron-acceptor cations of Etpy+ are each stacked parallel to the b axis, resulting in a columnar structure with segregated moieties. The crystal packing is stabilized by a three-dimensional O-H⋯N hydrogen-bonding network between the oxonium ions and the cyanide ligands of [Fe(CN)6]4-.
| Medienart: |
E-Artikel |
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| Erscheinungsjahr: |
2017 |
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| Erschienen: |
2017 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:73 |
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| Enthalten in: |
Acta crystallographica. Section E, Crystallographic communications - 73(2017), Pt 2 vom: 01. Feb., Seite 219-222 |
| Sprache: |
Englisch |
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| Beteiligte Personen: |
Tanaka, Rikako [VerfasserIn] |
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| Links: |
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| Themen: |
Crystal structure |
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| Anmerkungen: |
Date Revised 30.09.2020 published: Electronic-eCollection Citation Status PubMed-not-MEDLINE |
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| doi: |
10.1107/S2056989017000810 |
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| funding: |
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| Förderinstitution / Projekttitel: |
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| PPN (Katalog-ID): |
NLM269118535 |
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| 245 | 1 | 0 | |a Crystal structure of bis-(1-ethyl-pyridinium) dioxonium hexa-cyanidoferrate(II) |
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| 500 | |a Date Revised 30.09.2020 | ||
| 500 | |a published: Electronic-eCollection | ||
| 500 | |a Citation Status PubMed-not-MEDLINE | ||
| 520 | |a The title compound, (C7H10N)2(H3O)2[Fe(CN)6] or (Etpy)2(H3O)2[Fe(CN)6] (Etpy+ is 1-ethyl-pyridinium), crystallizes in the space group Pnnm. The FeII atom of the [Fe(CN)6]4- anion lies on a site with site symmetry ..2/m, and has an octa-hedral coordination sphere defined by six cyanido ligands. Both the Etpy+ and the oxonium cations are located on a mirror plane. In the crystal, electron-donor anions of [Fe(CN)6]4- and electron-acceptor cations of Etpy+ are each stacked parallel to the b axis, resulting in a columnar structure with segregated moieties. The crystal packing is stabilized by a three-dimensional O-H⋯N hydrogen-bonding network between the oxonium ions and the cyanide ligands of [Fe(CN)6]4- | ||
| 650 | 4 | |a Journal Article | |
| 650 | 4 | |a crystal structure | |
| 650 | 4 | |a ethylpyridinium ion | |
| 650 | 4 | |a hexacyanidoferrate(II) | |
| 650 | 4 | |a hydrogen bonds | |
| 650 | 4 | |a molecular salt | |
| 650 | 4 | |a oxonium ion | |
| 700 | 1 | |a Matsushita, Nobuyuki |e verfasserin |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Acta crystallographica. Section E, Crystallographic communications |d 2015 |g 73(2017), Pt 2 vom: 01. Feb., Seite 219-222 |w (DE-627)NLM246464437 |x 2056-9890 |7 nnns |
| 773 | 1 | 8 | |g volume:73 |g year:2017 |g number:Pt 2 |g day:01 |g month:02 |g pages:219-222 |
| 856 | 4 | 0 | |u http://dx.doi.org/10.1107/S2056989017000810 |3 Volltext |
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