Synthesis of 6H-Benzo[c]chromenes via Palladium-Catalyzed Intramolecular Dehydrogenative Coupling of Two Aryl C-H Bonds
The palladium-catalyzed intramolecular C-H/C-H coupling reaction of two simple arenes to generate 6H-benzo[c]chromenes has been reported for the first time. The approach features broad substrate scope and good tolerance of functional groups and uses molecular oxygen as the terminal oxidant. The high efficiency of the approach is verified by concise total synthesis of natural product cannabinol.
| Medienart: |
E-Artikel |
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| Erscheinungsjahr: |
2017 |
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| Erschienen: |
2017 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:19 |
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| Enthalten in: |
Organic letters - 19(2017), 4 vom: 17. Feb., Seite 798-801 |
| Sprache: |
Englisch |
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| Beteiligte Personen: |
Guo, Dong-Dong [VerfasserIn] |
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| Links: |
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| Themen: |
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| Anmerkungen: |
Date Completed 08.06.2018 Date Revised 08.06.2018 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
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| doi: |
10.1021/acs.orglett.6b03763 |
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| funding: |
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| Förderinstitution / Projekttitel: |
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| PPN (Katalog-ID): |
NLM268534950 |
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| 500 | |a published: Print-Electronic | ||
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| 520 | |a The palladium-catalyzed intramolecular C-H/C-H coupling reaction of two simple arenes to generate 6H-benzo[c]chromenes has been reported for the first time. The approach features broad substrate scope and good tolerance of functional groups and uses molecular oxygen as the terminal oxidant. The high efficiency of the approach is verified by concise total synthesis of natural product cannabinol | ||
| 650 | 4 | |a Journal Article | |
| 650 | 4 | |a Research Support, Non-U.S. Gov't | |
| 700 | 1 | |a Li, Bin |e verfasserin |4 aut | |
| 700 | 1 | |a Wang, Da-Yu |e verfasserin |4 aut | |
| 700 | 1 | |a Gao, Ya-Ru |e verfasserin |4 aut | |
| 700 | 1 | |a Guo, Shi-Huan |e verfasserin |4 aut | |
| 700 | 1 | |a Pan, Gao-Fei |e verfasserin |4 aut | |
| 700 | 1 | |a Wang, Yong-Qiang |e verfasserin |4 aut | |
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