Encapsulation of Fe3O4 Nanoparticles into N, S co-Doped Graphene Sheets with Greatly Enhanced Electrochemical Performance

Particular N, S co-doped graphene/Fe3O4 hybrids have been successfully synthesized by the combination of a simple hydrothermal process and a subsequent carbonization heat treatment. The nanostructures exhibit a unique composite architecture, with uniformly dispersed Fe3O4 nanoparticles and N, S co-doped graphene encapsulant. The particular porous characteristics with many meso/micro holes/pores, the highly conductive N, S co-doped graphene, as well as the encapsulating N, S co-doped graphene with the high-level nitrogen and sulfur doping, lead to excellent electrochemical performance of the electrode. The N-S-G/Fe3O4 composite electrode exhibits a high initial reversible capacity of 1362.2 mAhg(-1), a high reversible specific capacity of 1055.20 mAhg(-1) after 100 cycles, and excellent cycling stability and rate capability, with specific capacity of 556.69 mAhg(-1) when cycled at the current density of 1000 mAg(-1), indicating that the N-S-G/Fe3O4 composite is a promising anode candidate for Li-ion batteries.

Medienart:

E-Artikel

Erscheinungsjahr:

2016

Erschienen:

2016

Enthalten in:

Zur Gesamtaufnahme - volume:6

Enthalten in:

Scientific reports - 6(2016) vom: 14. Juni, Seite 27957

Sprache:

Englisch

Beteiligte Personen:

Yang, Zunxian [VerfasserIn]
Qian, Kun [VerfasserIn]
Lv, Jun [VerfasserIn]
Yan, Wenhuan [VerfasserIn]
Liu, Jiahui [VerfasserIn]
Ai, Jingwei [VerfasserIn]
Zhang, Yuxiang [VerfasserIn]
Guo, Tailiang [VerfasserIn]
Zhou, Xiongtu [VerfasserIn]
Xu, Sheng [VerfasserIn]
Guo, Zaiping [VerfasserIn]

Links:

Volltext

Themen:

Journal Article
Research Support, Non-U.S. Gov't

Anmerkungen:

Date Completed 11.04.2018

Date Revised 13.11.2018

published: Electronic

Citation Status PubMed-not-MEDLINE

doi:

10.1038/srep27957

funding:

Förderinstitution / Projekttitel:

PPN (Katalog-ID):

NLM261345761