tert-Butyl Nitrite : Organic Redox Cocatalyst for Aerobic Aldehyde-Selective Wacker-Tsuji Oxidation
An aldehyde-selective aerobic Wacker-Tsuji oxidation is developed. Using tert-butyl nitrite as a simple organic redox cocatalyst instead of copper or silver salts, a variety of aldehydes were achieved as major products in up to 30/1 regioselectivity as well as good to high yields at room temperature.
| Medienart: |
E-Artikel |
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| Erscheinungsjahr: |
2016 |
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| Erschienen: |
2016 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:18 |
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| Enthalten in: |
Organic letters - 18(2016), 11 vom: 03. Juni, Seite 2700-3 |
| Sprache: |
Englisch |
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| Beteiligte Personen: |
Ning, Xiao-Shan [VerfasserIn] |
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| Links: |
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| Themen: |
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| Anmerkungen: |
Date Completed 07.06.2018 Date Revised 07.06.2018 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
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| doi: |
10.1021/acs.orglett.6b01165 |
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| funding: |
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| Förderinstitution / Projekttitel: |
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| PPN (Katalog-ID): |
NLM260458805 |
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| 520 | |a An aldehyde-selective aerobic Wacker-Tsuji oxidation is developed. Using tert-butyl nitrite as a simple organic redox cocatalyst instead of copper or silver salts, a variety of aldehydes were achieved as major products in up to 30/1 regioselectivity as well as good to high yields at room temperature | ||
| 650 | 4 | |a Journal Article | |
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| 700 | 1 | |a Yao, Chuan-Zhi |e verfasserin |4 aut | |
| 700 | 1 | |a Chen, Xian-Min |e verfasserin |4 aut | |
| 700 | 1 | |a Kang, Yan-Biao |e verfasserin |4 aut | |
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