Trigonal Planar [HgSe3](4-) Unit : A New Kind of Basic Functional Group in IR Nonlinear Optical Materials with Large Susceptibility and Physicochemical Stability
A new mercury selenide BaHgSe2 was synthesized. This air-stable compound displays a large nonlinear optical (NLO) response and melts congruently. The structure contains chains of corner-sharing [HgSe3](4-) anions in the form of trigonal planar units, which may serve as a new kind of basic functional group in IR NLO materials to confer large NLO susceptibilities and physicochemical stability. Such trigonal planar units may inspire a path to finding new classes of IR NLO materials of practical utility that are totally different from traditional chalcopyrite materials.
| Medienart: |
E-Artikel |
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| Erscheinungsjahr: |
2016 |
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| Erschienen: |
2016 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:138 |
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| Enthalten in: |
Journal of the American Chemical Society - 138(2016), 19 vom: 18. Mai, Seite 6135-8 |
| Sprache: |
Englisch |
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| Beteiligte Personen: |
Li, Chao [VerfasserIn] |
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| Anmerkungen: |
Date Completed 18.04.2018 Date Revised 18.04.2018 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
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| doi: |
10.1021/jacs.6b03107 |
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| funding: |
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| Förderinstitution / Projekttitel: |
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| PPN (Katalog-ID): |
NLM259977934 |
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| 245 | 1 | 0 | |a Trigonal Planar [HgSe3](4-) Unit |b A New Kind of Basic Functional Group in IR Nonlinear Optical Materials with Large Susceptibility and Physicochemical Stability |
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| 500 | |a Date Revised 18.04.2018 | ||
| 500 | |a published: Print-Electronic | ||
| 500 | |a Citation Status PubMed-not-MEDLINE | ||
| 520 | |a A new mercury selenide BaHgSe2 was synthesized. This air-stable compound displays a large nonlinear optical (NLO) response and melts congruently. The structure contains chains of corner-sharing [HgSe3](4-) anions in the form of trigonal planar units, which may serve as a new kind of basic functional group in IR NLO materials to confer large NLO susceptibilities and physicochemical stability. Such trigonal planar units may inspire a path to finding new classes of IR NLO materials of practical utility that are totally different from traditional chalcopyrite materials | ||
| 650 | 4 | |a Journal Article | |
| 650 | 4 | |a Research Support, Non-U.S. Gov't | |
| 700 | 1 | |a Yin, Wenlong |e verfasserin |4 aut | |
| 700 | 1 | |a Gong, Pifu |e verfasserin |4 aut | |
| 700 | 1 | |a Li, Xiaoshuang |e verfasserin |4 aut | |
| 700 | 1 | |a Zhou, Molin |e verfasserin |4 aut | |
| 700 | 1 | |a Mar, Arthur |e verfasserin |4 aut | |
| 700 | 1 | |a Lin, Zheshuai |e verfasserin |4 aut | |
| 700 | 1 | |a Yao, Jiyong |e verfasserin |4 aut | |
| 700 | 1 | |a Wu, Yicheng |e verfasserin |4 aut | |
| 700 | 1 | |a Chen, Chuangtian |e verfasserin |4 aut | |
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