A [3Fe-3S](3+) cluster with exclusively μ-sulfide donors
A [3Fe-3(μ-S)](3+) cluster is reported in which each ferric center has a distorted trigonal pyramidal geometry, with an S = 1/2 ground state for the cluster and unusually anisotropic hyperfine coupling constants as determined by variable temperature magnetometry and Mössbauer spectroscopy.
| Medienart: |
E-Artikel |
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| Erscheinungsjahr: |
2016 |
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| Erschienen: |
2016 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:52 |
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| Enthalten in: |
Chemical communications (Cambridge, England) - 52(2016), 6 vom: 21. Jan., Seite 1174-7 |
| Sprache: |
Englisch |
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| Beteiligte Personen: |
Lee, Yousoon [VerfasserIn] |
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| Links: |
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| Themen: |
Journal Article |
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| Anmerkungen: |
Date Completed 27.05.2016 Date Revised 05.01.2016 published: Print Citation Status PubMed-not-MEDLINE |
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| doi: |
10.1039/c5cc07813j |
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| funding: |
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| Förderinstitution / Projekttitel: |
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| PPN (Katalog-ID): |
NLM254966497 |
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| 520 | |a A [3Fe-3(μ-S)](3+) cluster is reported in which each ferric center has a distorted trigonal pyramidal geometry, with an S = 1/2 ground state for the cluster and unusually anisotropic hyperfine coupling constants as determined by variable temperature magnetometry and Mössbauer spectroscopy | ||
| 650 | 4 | |a Journal Article | |
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| 700 | 1 | |a Abboud, Khalil A |e verfasserin |4 aut | |
| 700 | 1 | |a García-Serres, Ricardo |e verfasserin |4 aut | |
| 700 | 1 | |a Shearer, Jason |e verfasserin |4 aut | |
| 700 | 1 | |a Murray, Leslie J |e verfasserin |4 aut | |
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