CH3NH3SnxPb(1-x)I3 Perovskite Solar Cells Covering up to 1060 nm

We report photovoltaic performances of all-solid state Sn/Pb halide-based perovskite solar cells. The cell has the following composition: F-doped SnO2 layered glass/compact titania layer/porous titania layer/CH3NH3SnxPb(1-x)I3/regioregular poly(3-hexylthiophene-2,5-diyl). Sn halide perovskite itself did not show photovoltaic properties. Photovoltaic properties were observed when PbI2 was added in SnI2. The best performance was obtained by using CH3NH3Sn0.5Pb0.5I3 perovskite. 4.18% efficiency with open circuit voltage 0.42 V, fill factor 0.50, and short circuit current 20.04 mA/cm(2) are reported. The edge of the incident photon to current efficiency curve reached 1060 nm, which was 260 nm red-shifted compared with that of CH3NH3PbI3 perovskite solar cells.

Medienart:

E-Artikel

Erscheinungsjahr:

2014

Erschienen:

2014

Enthalten in:

Zur Gesamtaufnahme - volume:5

Enthalten in:

The journal of physical chemistry letters - 5(2014), 6 vom: 20. März, Seite 1004-11

Sprache:

Englisch

Beteiligte Personen:

Ogomi, Yuhei [VerfasserIn]
Morita, Atsushi [VerfasserIn]
Tsukamoto, Syota [VerfasserIn]
Saitho, Takahiro [VerfasserIn]
Fujikawa, Naotaka [VerfasserIn]
Shen, Qing [VerfasserIn]
Toyoda, Taro [VerfasserIn]
Yoshino, Kenji [VerfasserIn]
Pandey, Shyam S [VerfasserIn]
Ma, Tingli [VerfasserIn]
Hayase, Shuzi [VerfasserIn]

Links:

Volltext

Themen:

Journal Article
Near-infrared
P3HT
Perovskite
Solar cells
Tin halide

Anmerkungen:

Date Completed 19.08.2015

Date Revised 14.08.2015

published: Print-Electronic

Citation Status PubMed-not-MEDLINE

doi:

10.1021/jz5002117

funding:

Förderinstitution / Projekttitel:

PPN (Katalog-ID):

NLM251809765