Oxidative coupling of benzylamines to imines by molecular oxygen catalyzed by cobalt(II) β-tetrakis(trifluoromethyl)-meso-tetraphenylporphyrin
Oxidative coupling of benzylamines to imines by molecular oxygen is efficiently realized in the presence of very low catalyst loadings of Co(II) β-tetrakis(trifluoromethyl)-meso-tetraphenylporphyrin. Due to the effect of four β-CF3 groups, the catalyst shows good selectivity and very high turnover number. The reaction is easily scaled up and may provide a convenient way to prepare many imines in large scale.
| Medienart: |
E-Artikel |
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| Erscheinungsjahr: |
2014 |
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| Erschienen: |
2014 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:79 |
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| Enthalten in: |
The Journal of organic chemistry - 79(2014), 18 vom: 19. Sept., Seite 8926-31 |
| Sprache: |
Englisch |
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| Beteiligte Personen: |
Zhao, Shuai [VerfasserIn] |
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| Links: |
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| Themen: |
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| Anmerkungen: |
Date Completed 27.02.2015 Date Revised 19.09.2014 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
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| doi: |
10.1021/jo5017212 |
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| funding: |
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| Förderinstitution / Projekttitel: |
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| PPN (Katalog-ID): |
NLM241349338 |
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| 245 | 1 | 0 | |a Oxidative coupling of benzylamines to imines by molecular oxygen catalyzed by cobalt(II) β-tetrakis(trifluoromethyl)-meso-tetraphenylporphyrin |
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| 500 | |a Date Revised 19.09.2014 | ||
| 500 | |a published: Print-Electronic | ||
| 500 | |a Citation Status PubMed-not-MEDLINE | ||
| 520 | |a Oxidative coupling of benzylamines to imines by molecular oxygen is efficiently realized in the presence of very low catalyst loadings of Co(II) β-tetrakis(trifluoromethyl)-meso-tetraphenylporphyrin. Due to the effect of four β-CF3 groups, the catalyst shows good selectivity and very high turnover number. The reaction is easily scaled up and may provide a convenient way to prepare many imines in large scale | ||
| 650 | 4 | |a Journal Article | |
| 700 | 1 | |a Liu, Chao |e verfasserin |4 aut | |
| 700 | 1 | |a Guo, Yong |e verfasserin |4 aut | |
| 700 | 1 | |a Xiao, Ji-Chang |e verfasserin |4 aut | |
| 700 | 1 | |a Chen, Qing-Yun |e verfasserin |4 aut | |
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