Synthesis of α-trifluoromethyl ketones via the Cu-catalyzed trifluoromethylation of silyl enol ethers using an electrophilic trifluoromethylating agent
A method has been developed for the synthesis of α-trifluoromethyl ketones via the Cu-catalyzed trifluoromethylation of silyl enol ethers with an electrophilic trifluoromethylating agent, which produces a trifluoromethyl radical.
| Medienart: |
E-Artikel |
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| Erscheinungsjahr: |
2014 |
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| Erschienen: |
2014 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:79 |
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| Enthalten in: |
The Journal of organic chemistry - 79(2014), 11 vom: 06. Juni, Seite 5145-52 |
| Sprache: |
Englisch |
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| Beteiligte Personen: |
Li, Lun [VerfasserIn] |
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| Links: |
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| Themen: |
Alcohols |
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| Anmerkungen: |
Date Completed 07.02.2015 Date Revised 06.06.2014 published: Print-Electronic Citation Status MEDLINE |
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| doi: |
10.1021/jo500713f |
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| funding: |
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| Förderinstitution / Projekttitel: |
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| PPN (Katalog-ID): |
NLM238332667 |
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| 520 | |a A method has been developed for the synthesis of α-trifluoromethyl ketones via the Cu-catalyzed trifluoromethylation of silyl enol ethers with an electrophilic trifluoromethylating agent, which produces a trifluoromethyl radical | ||
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| 650 | 7 | |a Hydrocarbons, Fluorinated |2 NLM | |
| 650 | 7 | |a Ketones |2 NLM | |
| 650 | 7 | |a Silanes |2 NLM | |
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| 700 | 1 | |a Guo, Yong |e verfasserin |4 aut | |
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