Preorganized assembly of three iron(II) or manganese(II) β-diketiminate complexes using a cyclophane ligand
A trinucleating cyclophane bearing three β-diketimine arms, and the corresponding iron(II) and manganese(II) complexes have been synthesized and characterized. The three metal ions are oriented towards the internal void space, and are coordinated by a N2Br2 donor set, in which a unique combination of μ(3), μ, and terminal coordination modes are observed for the halide donors.
Medienart: |
E-Artikel |
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Erscheinungsjahr: |
2013 |
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Erschienen: |
2013 |
Enthalten in: |
Zur Gesamtaufnahme - volume:49 |
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Enthalten in: |
Chemical communications (Cambridge, England) - 49(2013), 59 vom: 28. Juli, Seite 6635-7 |
Sprache: |
Englisch |
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Beteiligte Personen: |
Guillet, Gary L [VerfasserIn] |
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Links: |
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Themen: |
42Z2K6ZL8P |
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Anmerkungen: |
Date Completed 17.01.2014 Date Revised 27.06.2013 published: Print Citation Status MEDLINE |
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doi: |
10.1039/c3cc43395a |
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funding: |
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Förderinstitution / Projekttitel: |
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PPN (Katalog-ID): |
NLM228428165 |
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520 | |a A trinucleating cyclophane bearing three β-diketimine arms, and the corresponding iron(II) and manganese(II) complexes have been synthesized and characterized. The three metal ions are oriented towards the internal void space, and are coordinated by a N2Br2 donor set, in which a unique combination of μ(3), μ, and terminal coordination modes are observed for the halide donors | ||
650 | 4 | |a Journal Article | |
650 | 4 | |a Research Support, Non-U.S. Gov't | |
650 | 4 | |a Research Support, U.S. Gov't, Non-P.H.S. | |
650 | 7 | |a Benzene Derivatives |2 NLM | |
650 | 7 | |a Ferrous Compounds |2 NLM | |
650 | 7 | |a Imines |2 NLM | |
650 | 7 | |a Ligands |2 NLM | |
650 | 7 | |a Organometallic Compounds |2 NLM | |
650 | 7 | |a Manganese |2 NLM | |
650 | 7 | |a 42Z2K6ZL8P |2 NLM | |
700 | 1 | |a Sloane, Forrest T |e verfasserin |4 aut | |
700 | 1 | |a Ermert, David M |e verfasserin |4 aut | |
700 | 1 | |a Calkins, Matthew W |e verfasserin |4 aut | |
700 | 1 | |a Peprah, Marcus K |e verfasserin |4 aut | |
700 | 1 | |a Knowles, Elisabeth S |e verfasserin |4 aut | |
700 | 1 | |a Čižmár, Erik |e verfasserin |4 aut | |
700 | 1 | |a Abboud, Khalil A |e verfasserin |4 aut | |
700 | 1 | |a Meisel, Mark W |e verfasserin |4 aut | |
700 | 1 | |a Murray, Leslie J |e verfasserin |4 aut | |
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