Preorganized assembly of three iron(II) or manganese(II) β-diketiminate complexes using a cyclophane ligand

A trinucleating cyclophane bearing three β-diketimine arms, and the corresponding iron(II) and manganese(II) complexes have been synthesized and characterized. The three metal ions are oriented towards the internal void space, and are coordinated by a N2Br2 donor set, in which a unique combination of μ(3), μ, and terminal coordination modes are observed for the halide donors.

Medienart:

E-Artikel

Erscheinungsjahr:

2013

Erschienen:

2013

Enthalten in:

Zur Gesamtaufnahme - volume:49

Enthalten in:

Chemical communications (Cambridge, England) - 49(2013), 59 vom: 28. Juli, Seite 6635-7

Sprache:

Englisch

Beteiligte Personen:

Guillet, Gary L [VerfasserIn]
Sloane, Forrest T [VerfasserIn]
Ermert, David M [VerfasserIn]
Calkins, Matthew W [VerfasserIn]
Peprah, Marcus K [VerfasserIn]
Knowles, Elisabeth S [VerfasserIn]
Čižmár, Erik [VerfasserIn]
Abboud, Khalil A [VerfasserIn]
Meisel, Mark W [VerfasserIn]
Murray, Leslie J [VerfasserIn]

Links:

Volltext

Themen:

42Z2K6ZL8P
Benzene Derivatives
Ferrous Compounds
Imines
Journal Article
Ligands
Manganese
Organometallic Compounds
Research Support, Non-U.S. Gov't
Research Support, U.S. Gov't, Non-P.H.S.

Anmerkungen:

Date Completed 17.01.2014

Date Revised 27.06.2013

published: Print

Citation Status MEDLINE

doi:

10.1039/c3cc43395a

funding:

Förderinstitution / Projekttitel:

PPN (Katalog-ID):

NLM228428165