Ring-opening reaction of 2,5-dioctyldithieno[2,3-b:3',2'-d]thiophene in the presence of aryllithium reagents
In this paper, the ring-opening reaction of 2,5-dioctyldithieno[2,3-b:3',2'-d]thiophene with aryllithium in THF at low temperature to generate 2'-arylthio-3,3'-bithiophene-2-carbaldehydes is studied. Nine examples are explored and all the products are characterized by (1)H NMR, (13)C NMR and HRMS. The relative relationship between the structures of aryl groups and the efficiency of ring-opening reactions are discussed.
| Medienart: |
E-Artikel |
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| Erscheinungsjahr: |
2013 |
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| Erschienen: |
2013 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:9 |
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| Enthalten in: |
Beilstein journal of organic chemistry - 9(2013) vom: 07., Seite 767-74 |
| Sprache: |
Englisch |
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| Beteiligte Personen: |
Zhong, Hao [VerfasserIn] |
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| Links: |
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| Themen: |
2'-arylthio-3,3'-bithiophene-2-carbaldehyde |
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| Anmerkungen: |
Date Completed 17.06.2013 Date Revised 21.10.2021 published: Electronic-Print Citation Status PubMed-not-MEDLINE |
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| doi: |
10.3762/bjoc.9.87 |
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| funding: |
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| Förderinstitution / Projekttitel: |
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| PPN (Katalog-ID): |
NLM228344859 |
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| 245 | 1 | 0 | |a Ring-opening reaction of 2,5-dioctyldithieno[2,3-b:3',2'-d]thiophene in the presence of aryllithium reagents |
| 264 | 1 | |c 2013 | |
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| 500 | |a Date Completed 17.06.2013 | ||
| 500 | |a Date Revised 21.10.2021 | ||
| 500 | |a published: Electronic-Print | ||
| 500 | |a Citation Status PubMed-not-MEDLINE | ||
| 520 | |a In this paper, the ring-opening reaction of 2,5-dioctyldithieno[2,3-b:3',2'-d]thiophene with aryllithium in THF at low temperature to generate 2'-arylthio-3,3'-bithiophene-2-carbaldehydes is studied. Nine examples are explored and all the products are characterized by (1)H NMR, (13)C NMR and HRMS. The relative relationship between the structures of aryl groups and the efficiency of ring-opening reactions are discussed | ||
| 650 | 4 | |a Journal Article | |
| 650 | 4 | |a 2'-arylthio-3,3'-bithiophene-2-carbaldehyde | |
| 650 | 4 | |a aryllithium reagents | |
| 650 | 4 | |a dithieno[2,3-b:3',2'-d]thiophene | |
| 650 | 4 | |a nucleophilicity | |
| 650 | 4 | |a ring-opening reaction | |
| 700 | 1 | |a Shi, Jianwu |e verfasserin |4 aut | |
| 700 | 1 | |a Kang, Jianxun |e verfasserin |4 aut | |
| 700 | 1 | |a Wang, Shaomin |e verfasserin |4 aut | |
| 700 | 1 | |a Liu, Xinming |e verfasserin |4 aut | |
| 700 | 1 | |a Wang, Hua |e verfasserin |4 aut | |
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| 856 | 4 | 0 | |u http://dx.doi.org/10.3762/bjoc.9.87 |3 Volltext |
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