Asymmetric [3+2] annulation of allenes with maleimides catalyzed by dipeptide-derived phosphines : facile creation of functionalized bicyclic cyclopentenes containing two tertiary stereogenic centers

This journal is © The Royal Society of Chemistry 2012.

D-Threonine-L-tert-leucine-derived bifunctional phosphine, Cat. 11, catalyzed highly enantioselective [3+2] annulation of maleimides with allenes has been disclosed, allowing the synthesis of optically active functionalized bicyclic cyclopentenes containing two tertiary stereogenic centers in good to high yields along with good to high enantioselectivities.

Medienart:

E-Artikel

Erscheinungsjahr:

2012

Erschienen:

2012

Enthalten in:

Zur Gesamtaufnahme - volume:48

Enthalten in:

Chemical communications (Cambridge, England) - 48(2012), 7 vom: 25. Jan., Seite 970-2

Sprache:

Englisch

Beteiligte Personen:

Zhao, Qianyi [VerfasserIn]
Han, Xiaoyu [VerfasserIn]
Wei, Yin [VerfasserIn]
Shi, Min [VerfasserIn]
Lu, Yixin [VerfasserIn]

Links:

Volltext

Themen:

Alkadienes
Bridged Bicyclo Compounds
Cyclopentanes
Dipeptides
Journal Article
Maleimides
Phosphines
Research Support, Non-U.S. Gov't

Anmerkungen:

Date Completed 17.04.2012

Date Revised 25.11.2016

published: Print-Electronic

Citation Status MEDLINE

doi:

10.1039/c2cc16904e

funding:

Förderinstitution / Projekttitel:

PPN (Katalog-ID):

NLM213609878