One-pot regioselective synthesis and X-ray crystal structure of a stable [60]fullerene trisadduct with the e(edge),e(face),trans-1 addition pattern

This journal is © The Royal Society of Chemistry 2011.

The Bingel functionalisation of C(60) with a structurally novel tether equipped with three reactive malonate groups afforded a C(2v)-symmetrical e(edge),e(face),trans-1 trisadduct in a complete regioselective manner and in an excellent yield of 65%. The [60]fullerene trisadduct showed pronounced ability to crystallise and gave X-ray quality single crystals for analysis.

Medienart:

E-Artikel

Erscheinungsjahr:

2011

Erschienen:

2011

Enthalten in:

Zur Gesamtaufnahme - volume:47

Enthalten in:

Chemical communications (Cambridge, England) - 47(2011), 43 vom: 21. Nov., Seite 11948-50

Sprache:

Englisch

Beteiligte Personen:

Riala, Maria [VerfasserIn]
Markoulides, Marios S [VerfasserIn]
Moushi, Eleni E [VerfasserIn]
Chronakis, Nikos [VerfasserIn]

Links:

Volltext

Themen:

Journal Article

Anmerkungen:

Date Completed 21.02.2012

Date Revised 25.10.2011

published: Print-Electronic

Citation Status PubMed-not-MEDLINE

doi:

10.1039/c1cc15596b

funding:

Förderinstitution / Projekttitel:

PPN (Katalog-ID):

NLM211973513