Isoquinoline-based chiral monodentate N-heterocyclic carbenes
C(1)-symmetric isoquinoline-based chiral diaminocarbene ligands (MIQ) have been developed to block three quadrants of the metal coordination sphere, complementing C(2)-symmetric biisoquinoline-based ligands (BIQ). MIQ-Cu complexes catalyzed conjugate borylation of various α,β-unsaturated amides in good yields (82-99%) and enantioselectivities (75-87% ee).
| Medienart: |
E-Artikel |
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| Erscheinungsjahr: |
2010 |
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| Erschienen: |
2010 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:46 |
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| Enthalten in: |
Chemical communications (Cambridge, England) - 46(2010), 40 vom: 28. Okt., Seite 7525-7 |
| Sprache: |
Englisch |
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| Beteiligte Personen: |
Hirsch-Weil, Dimitri [VerfasserIn] |
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| Links: |
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| Themen: |
2465-56-7 |
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| Anmerkungen: |
Date Completed 31.01.2011 Date Revised 21.11.2013 published: Print-Electronic Citation Status MEDLINE |
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| doi: |
10.1039/c0cc02211j |
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| funding: |
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| Förderinstitution / Projekttitel: |
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| PPN (Katalog-ID): |
NLM201510545 |
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| 520 | |a C(1)-symmetric isoquinoline-based chiral diaminocarbene ligands (MIQ) have been developed to block three quadrants of the metal coordination sphere, complementing C(2)-symmetric biisoquinoline-based ligands (BIQ). MIQ-Cu complexes catalyzed conjugate borylation of various α,β-unsaturated amides in good yields (82-99%) and enantioselectivities (75-87% ee) | ||
| 650 | 4 | |a Journal Article | |
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| 650 | 4 | |a Research Support, U.S. Gov't, Non-P.H.S. | |
| 650 | 7 | |a Amides |2 NLM | |
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| 700 | 1 | |a Hong, Sukwon |e verfasserin |4 aut | |
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