Azide groups in high oxidation state Mn carboxylate chemistry : a new Mn(11) complex and its conversion to a Mn(25) azide complex with Me(3)SiN(3)

A new high oxidation state Mn(III/IV)(11) carboxylate complex has been prepared and then converted to a Mn(II/III)(25) azide/carboxylate cluster with Me(3)SiN(3); the Mn(25) product is the initial example of a higher oxidation state Mn azide complex not stabilized by any chelate ligands.

Medienart:

E-Artikel

Erscheinungsjahr:

2009

Erschienen:

2009

Enthalten in:

Zur Gesamtaufnahme - year:2009

Enthalten in:

Chemical communications (Cambridge, England) - (2009), 20 vom: 28. Mai, Seite 2839-41

Sprache:

Englisch

Beteiligte Personen:

Stamatatos, Theocharis C [VerfasserIn]
Vinslava, Alina [VerfasserIn]
Abboud, Khalil A [VerfasserIn]
Christou, George [VerfasserIn]

Links:

Volltext

Themen:

42Z2K6ZL8P
Azides
Azidotrimethylsilane
Carboxylic Acids
Journal Article
Ligands
Manganese
Research Support, U.S. Gov't, Non-P.H.S.
Silanes

Anmerkungen:

Date Completed 21.07.2009

Date Revised 21.11.2013

published: Print-Electronic

Citation Status MEDLINE

doi:

10.1039/b902016k

funding:

Förderinstitution / Projekttitel:

PPN (Katalog-ID):

NLM188476261