Carbon tetrabromide-mediated carbon-sulfur bond formation via a sulfenyl bromide intermediate
In the presence of carbon tetrabromide, a variety of dithiocarbamates, xanthates, dithioesters, and thioethers were prepared in one pot by reacting the corresponding dithioic acids or thiols with active methylene compounds/indole derivatives under mild conditions. The formation of a sulfenyl bromide intermediate is proposed as the key step, which initiates the C-S bond formation.
| Medienart: |
E-Artikel |
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| Erscheinungsjahr: |
2008 |
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| Erschienen: |
2008 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:10 |
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| Enthalten in: |
Organic letters - 10(2008), 12 vom: 19. Juni, Seite 2485-8 |
| Sprache: |
Englisch |
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| Beteiligte Personen: |
Tan, Jing [VerfasserIn] |
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| Links: |
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| Themen: |
Carbon tetrabromide |
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| Anmerkungen: |
Date Completed 07.08.2008 Date Revised 24.11.2016 published: Print-Electronic Citation Status MEDLINE |
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| doi: |
10.1021/ol800765s |
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| funding: |
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| Förderinstitution / Projekttitel: |
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| PPN (Katalog-ID): |
NLM179614924 |
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| 520 | |a In the presence of carbon tetrabromide, a variety of dithiocarbamates, xanthates, dithioesters, and thioethers were prepared in one pot by reacting the corresponding dithioic acids or thiols with active methylene compounds/indole derivatives under mild conditions. The formation of a sulfenyl bromide intermediate is proposed as the key step, which initiates the C-S bond formation | ||
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| 650 | 7 | |a Hydrocarbons, Brominated |2 NLM | |
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| 700 | 1 | |a Cheng, Xin |e verfasserin |4 aut | |
| 700 | 1 | |a Liu, Qun |e verfasserin |4 aut | |
| 700 | 1 | |a Yuan, Hongjuan |e verfasserin |4 aut | |
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