Nonlinear optical chromophores with pyrrole moieties as the conjugated bridge : enhanced NLO effects and interesting optical behavior

A series of nonlinear optical (NLO) chromophores were successfully prepared, in which pyrrole moieties were the conjugated bridge. In comparison with their analogues containing furan or thiophene groups as the bridge, these chromophores demonstrated similar or enhanced NLO effects (up to 3.3 times) and interesting optical behavior. While the acceptor groups were malononitrile (Mal), 3-phenyl-5-isoxazolone (Iso), and 1,3-diethylthiobarbituric acid (Bar), the chromophores exhibited much blue-shifted maximum absorption wavelengths (lambda max) (up to 36 nm); however, the lambda max of the chromophore containing tricyanovinyldihydrofuran (TCF) as acceptor became much longer than that of the analogue (up to 75 nm).

Medienart:

E-Artikel

Erscheinungsjahr:

2008

Erschienen:

2008

Enthalten in:

Zur Gesamtaufnahme - volume:112

Enthalten in:

The journal of physical chemistry. B - 112(2008), 15 vom: 17. Apr., Seite 4545-51

Sprache:

Englisch

Beteiligte Personen:

Li, Qianqian [VerfasserIn]
Lu, Changgui [VerfasserIn]
Zhu, Jing [VerfasserIn]
Fu, Enqin [VerfasserIn]
Zhong, Cheng [VerfasserIn]
Li, Suyue [VerfasserIn]
Cui, Yiping [VerfasserIn]
Qin, Jingui [VerfasserIn]
Li, Zhen [VerfasserIn]

Links:

Volltext

Themen:

Journal Article

Anmerkungen:

Date Completed 23.06.2008

Date Revised 11.04.2008

published: Print-Electronic

Citation Status PubMed-not-MEDLINE

doi:

10.1021/jp0768322

funding:

Förderinstitution / Projekttitel:

PPN (Katalog-ID):

NLM178488585