The structural determination of endohedral metallofullerene Gd@C(82) by XANES

Although the Gd ion in GdC(82) has been shown to lie above the C-C bond on the C(2) axis as an anomalous structure from the MEM/Rietveld analysis, the present XANES study reveals that it lies above the hexagon on the C(2) axis as a normal structure, and Gd oscillates around its equilibrium position with an amplitude increasing with temperature increase.

Medienart:

E-Artikel

Erscheinungsjahr:

2008

Erschienen:

2008

Enthalten in:

Zur Gesamtaufnahme - year:2008

Enthalten in:

Chemical communications (Cambridge, England) - (2008), 4 vom: 28. Jan., Seite 474-6

Sprache:

Englisch

Beteiligte Personen:

Liu, Lei [VerfasserIn]
Gao, Bin [VerfasserIn]
Chu, Wangsheng [VerfasserIn]
Chen, Dongliang [VerfasserIn]
Hu, Tiandou [VerfasserIn]
Wang, Chunru [VerfasserIn]
Dunsch, Lothar [VerfasserIn]
Marcelli, Augusto [VerfasserIn]
Luo, Yi [VerfasserIn]
Wu, Ziyu [VerfasserIn]

Links:

Volltext

Themen:

AU0V1LM3JT
Fullerenes
Gadolinium
Journal Article
Research Support, Non-U.S. Gov't

Anmerkungen:

Date Completed 01.04.2008

Date Revised 21.11.2013

published: Print-Electronic

Citation Status MEDLINE

doi:

10.1039/b714603e

funding:

Förderinstitution / Projekttitel:

PPN (Katalog-ID):

NLM17679994X