Substituent effects of the N,N-dimethyl- sulfamoyl group on the 1H and 13C NMR spectra of positional isomers of quinolines
Copyright (c) 2007 John Wiley & Sons, Ltd..
The complete 1H and 13C NMR spectral assignments of seven positional isomers of N,N-dimethylsulfamoylquinolines 2-8 and quinoline have been made using 1D and 2D NMR techniques, including COSY, HMQC and HMBC experiments. Deltadelta(H) and Deltadelta(C) substituent effects induced by the sulfamoyl group were determined. The sulfamoyl substituent affects proton and carbon chemical shifts both in the parent and in the fused (pyridine or benzene) ring.
Medienart: |
E-Artikel |
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Erscheinungsjahr: |
2008 |
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Erschienen: |
2008 |
Enthalten in: |
Zur Gesamtaufnahme - volume:46 |
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Enthalten in: |
Magnetic resonance in chemistry : MRC - 46(2008), 2 vom: 19. Feb., Seite 182-5 |
Sprache: |
Englisch |
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Beteiligte Personen: |
Maślankiewicz, Andrzej [VerfasserIn] |
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Themen: |
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Anmerkungen: |
Date Completed 08.04.2008 Date Revised 20.07.2009 published: Print Citation Status MEDLINE |
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Förderinstitution / Projekttitel: |
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PPN (Katalog-ID): |
NLM17582732X |
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520 | |a The complete 1H and 13C NMR spectral assignments of seven positional isomers of N,N-dimethylsulfamoylquinolines 2-8 and quinoline have been made using 1D and 2D NMR techniques, including COSY, HMQC and HMBC experiments. Deltadelta(H) and Deltadelta(C) substituent effects induced by the sulfamoyl group were determined. The sulfamoyl substituent affects proton and carbon chemical shifts both in the parent and in the fused (pyridine or benzene) ring | ||
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