From controllable attached isolation moieties to possibly highly efficient nonlinear optical main-chain polyurethanes containing indole-based chromophores

For the first time, the indole-based NLO chromophores were embedded into the polymer main chain, and different isolation groups were attached to their donor side with the efforts of adjusting the NLO properties of the resultant main-chain polyurethanes, according to the site isolation principle. Thanks to the main-chain structure and the advantages of the indole-based chromophores, all the polymers show excellent transparency, good processability, thermal stability, and relatively good NLO effects. The tested NLO properties of the polymers demonstrate that there is a suitable isolation group present for the sulfonyl-based chromophore to boost its microscopic beta value to a possibly higher macroscopic NLO property efficiently.

Medienart:

Artikel

Erscheinungsjahr:

2007

Erschienen:

2007

Enthalten in:

Zur Gesamtaufnahme - volume:111

Enthalten in:

The journal of physical chemistry. B - 111(2007), 3 vom: 25. Jan., Seite 508-14

Sprache:

Englisch

Beteiligte Personen:

Li, Qianqian [VerfasserIn]
Li, Zhen [VerfasserIn]
Zeng, Fanxin [VerfasserIn]
Gong, Wei [VerfasserIn]
Li, Zhong'an [VerfasserIn]
Zhu, Zhichao [VerfasserIn]
Zeng, Qi [VerfasserIn]
Yu, Shanshan [VerfasserIn]
Ye, Cheng [VerfasserIn]
Qin, Jingui [VerfasserIn]

Themen:

Journal Article

Anmerkungen:

Date Completed 01.05.2007

Date Revised 18.01.2007

published: Print

Citation Status PubMed-not-MEDLINE

Förderinstitution / Projekttitel:

PPN (Katalog-ID):

NLM167746359